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A SILICOALUMINOPHOSPAHTE ISOMERIZATION CATALYST

机译:硅铝磷酸盐异构化催化剂

摘要

A catalyst system for treating a hydrocarbonaceous feed comprising a matrix selected from the group consisting of alumina, silica alumina, titanium alumina and mixtures thereof; a support medium substantially uniformly distributed through said matrix comprising a SAPO-11 molecular sieve; and about 0.1 to about 1.0 wt % (based on the total weight of the catalyst system) of a catalytically active metal phase supported on said medium and comprising a metal selected from the group consisting of platinum, palladium, ruthenium, rhodium or mixtures thereof. The catalyst system is characterized in that said SAPO-11 molecular sieve has: a) a silica to alumina molar ratio of about 0.08 to about 0.24,- b) a phosphorous to alumina ratio of about 0.75 to about 0.83; c) a microsurface area of at least about 150m2/g; d) a crytallite size in the range of abouth 250 to about 600 angstroms, and e) a sodium content of less than about 2000 ppm weight.
机译:用于处理含烃进料的催化剂体系,其包含选自氧化铝,二氧化硅氧化铝,钛氧化铝及其混合物的基质;基本上均匀地分布在包括SAPO-11分子筛的所述基质中的支持介质;和约0.1至约1.0wt%(基于催化剂体系的总重量)负载在所述介质上并且包含选自铂,钯,钌,铑或它们的混合物的金属的催化活性金属相。该催化剂体系的特征在于所述SAPO-11分子筛具有:a)二氧化硅与氧化铝的摩尔比为约0.08至约0.24,-b)磷与氧化铝的比为约0.75至约0.83; c)至少约150m2 / g的微表面积; d)冰晶石尺寸在约250埃至约600埃的范围内,并且e)钠含量小于约2000ppm重量。

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