首页> 外国专利> METHOD FOR CONTINUOUSLY PRODUCING POLYAMIDE OLIGOMERS AND FOR PRODUCING SEMICRYSTALLINE OR AMORPHOUS POLYAMIDES THAT CAN BE THERMOPLASTICALLY PROCESSED

METHOD FOR CONTINUOUSLY PRODUCING POLYAMIDE OLIGOMERS AND FOR PRODUCING SEMICRYSTALLINE OR AMORPHOUS POLYAMIDES THAT CAN BE THERMOPLASTICALLY PROCESSED

机译:连续生产聚酰胺低聚物以及生产可热塑加工的半结晶或非晶态聚酰胺的方法

摘要

The present invention relates to a continuous process for preparing polyamide oligomers. This is accomplished by continuously conveying an aqueous solution of the polyamide-forming monomer from a storage vessel to an oligomerization reactor, heating the aqueous solution to a temperature above the dissolution or storage temperature so that the conversion of the monomer to the polyamide oligomer does not exceed a maximum value Limiting the residence time of the monomer solution in the oligomerization reactor and / or adjusting the water pressure or partial vapor pressure so that the polyamide oligomer formed and / or the polyamide oligomer formed is not phase separated or spontaneously crystallized in solid form, and oligomerization And continuously discharging the polyamide oligomer from the reactor. Polyamide oligomers which can be prepared by this process can be provided continuously in a mixture with water in a semi-crystalline or amorphous thermoplastic processable polyamide preparation process, followed by post-condensation to provide polyamides. The polyamides can be used in the production of molded articles by injection molding, multicomponent injection molding, injection molding / welding, extrusion, coextrusion, blow molding or thermoforming.
机译:本发明涉及一种制备聚酰胺低聚物的连续方法。这是通过将聚酰胺形成单体的水溶液从存储容器连续输送到低聚反应器,将水溶液加热到高于溶解或存储温度的温度来完成的,这样就不会将单体转化为聚酰胺低聚物。超过最大值限制单体溶液在低聚反应器中的停留时间和/或调节水压或部分蒸气压,以使形成的聚酰胺低聚物和/或形成的聚酰胺低聚物不发生相分离或以固体形式自发结晶以及低聚反应,并从反应器中连续排出聚酰胺低聚物。可以通过该方法制备的聚酰胺低聚物在半结晶或无定形热塑性可加工聚酰胺制备方法中与水混合连续地提供,随后缩合以提供聚酰胺。聚酰胺可用于通过注塑,多组分注塑,注塑/焊接,挤出,共挤出,吹塑或热成型的模制品的生产。

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