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BIMETAL-EXCHANGED ZEOLITE BETA FROM ORGANOTEMPLATE-FREE SYNTHESIS AND USE THEREOF IN THE SELECTIVE CATALYTIC REDUCTION OF NOX

机译:无需有机模板合成的双金属交换沸石贝塔及其在NOx选择性催化还原中的应用

摘要

SUMMARY OF THE INVENTION2 And X2O31. A method for producing a zeolite material having a BEA-2One or more sources of X2O3 RTI ID = 0.0 of: /RTI (2) crystallizing the mixture obtained in step (1); (3) performing an ion-exchange procedure with copper for the zeolite material having the BEA-type framework structure obtained in step (2); And (4) performing an ion exchange procedure with Fe for the Cu ion-exchanged zeolite material obtained in step (3), wherein Y is a tetravalent element, X is a trivalent element, Wherein the mixture provided in step (1) and crystallized in step (2) further comprises a column comprising at least one zeolite material having a BEA-type framework structure, wherein step (2) Wherein the crystallized mixture does not contain an organic template as a structure-directing agent, and wherein the zeolite material itself having a BEA backbone structure, and in particular NO (NO) by selective catalytic reduction (SCR)X/RTI
机译:发明内容 2 和X 2 O 3 1。一种具有BEA- 2 一个或多个X 2 O 3 来源的沸石材料的制造方法: (2)使步骤(1)中获得的混合物结晶; (3)对步骤(2)中得到的具有BEA型骨架结构的沸石材料用铜进行离子交换步骤。 (4)对步骤(3)中得到的Cu离子交换沸石材料,与Fe进行离子交换步骤,其中Y为四价元素,X为三价元素,其中步骤(1)中提供并结晶的混合物步骤(2)中的沸石进一步包括包含至少一种具有BEA型骨架结构的沸石材料的塔,其中步骤(2)中,结晶混合物不包含有机模板作为结构导向剂,并且其中沸石材料本身具有BEA主链结构,尤其是通过选择性催化还原(SCR) X 的NO(NO)

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