首页> 外国专利> - PROCESS FOR CONTROLLED HYDROLYSIS AND CONDENSATION OF EPOXY-FUNCTIONAL ORGANOSILANES AND THE COCONDENSATION THEREOF WITH FURTHER ORGANOFUNCTIONAL ALKOXYSILANES

- PROCESS FOR CONTROLLED HYDROLYSIS AND CONDENSATION OF EPOXY-FUNCTIONAL ORGANOSILANES AND THE COCONDENSATION THEREOF WITH FURTHER ORGANOFUNCTIONAL ALKOXYSILANES

机译:-环氧官能有机硅的受控水解和缩合及其与其他有机官能烷烃的共缩合过程

摘要

Using The present invention uses the water of an alkoxy functional group 1 from 0.001 to 5 moles per mole of the used silane, acid except as any additional hydrolysis or condensation catalyst is also a hydrolysis catalyst and condensation component of not do, the condensed water formed in the reaction Si-OB and / or Si-O-Si to that of, based on the combined epoxy of the formula I - functional silane and add one or more of formula II optionally in the organofunctional It relates to an adjustment method of silane hydrolysis and condensation. [Formula I] Wherein, R 1 is or img file="112010009640116-pct00015.jpg" he = "21" id = "i0015" img-format = "jpg" wi = "65" and / group, And R, R 'and R' 'groups are the same or different and are each a hydrogen (H), or 1 to 6 carbon linear, branched or cyclic optionally substituted alkyl group having atoms, A and A 'groups are the same or different and each is a divalent alkyl group having 1 to 10 carbon atoms, R 2 and the groups are the same or different and each, R 2 is from 1 to 20 carbon linear, branched or cyclic optionally substituted alkyl group, m is 0 or 1. [Formula II] Wherein, R 2 is an organofunctional group as already defined above, R 'is methyl, R groups are each independently hydrogen, or one to six carbon atoms having linear, branched, or cyclic alkyl group, n is 0 or 1. ;
机译:使用本发明使用的烷氧基官能团1的水为每摩尔所用的硅烷,酸0.001至5摩尔,除了任何另外的水解或缩合催化剂也是水解催化剂并且缩合组分不起作用外,形成的冷凝水为0.001至5摩尔在Si-OB和/或Si-O-Si的反应中,基于式I的结合的环氧-官能硅烷并任选地在有机官能团中添加一种或多种式II的硅烷。涉及硅烷的调节方法水解和缩合。 [式I]其中,R 1 是或 file =“ 112010009640116-pct00015.jpg”他=“ 21” id =“ i0015” img-format =“ jpg” wi =“ 65” R,R'和R''基团相同或不同,并且各自为氢(H)或具有原子A和A'的1-6个碳原子的直链,支链或环状任选取代的烷基基团相同或不同,并且每个是具有1至10个碳原子的二价烷基,R 2 ,并且基团相同或不同,并且每个R 2 是从1至20个碳的直链,支链或环状的任选取代的烷基,m为0或1。[式II]其中,R 2 是如上已经定义的有机官能团,R'是甲基, R基团各自独立地为氢或具有直链,支链或环状烷基的1-6个碳原子,n为0或1。

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