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- - Method for manufacturing of meso-microporous mordenite in form of plate and meso-microporous mordenite in form of plate thereby

机译:-制造板状的中微孔丝光沸石和由此制得的板状的中微孔丝光沸石的方法

摘要

The present invention relates to a method for producing meso-microporous plate-like mordenite and meso-microspheroidal plate-like mordenite produced thereby, and more particularly to a mordenite precursor having a molar ratio of SiO 2 / Al 2 O 3 of 25 to 35 A manufacturing step (step 1); Mixing the mordenite precursor of step 1 with a casting mold (step 2); Crystallizing mordenite in the mixed solution of step 2 (step 3); And a step (4) of heat-treating the crystallized mixed solution of step 3 to remove the cast body (4), and a method for producing the meso-microspheroidal plate-like mordenite. The present invention can produce a mordenite having a plate-like shape at the same time as the plate-shaped meso-micropores by a simple method. At this time, since an inexpensive surfactant or a hydrophilic polymer is used and organic silane is not added, it can be economically provided because it is commercially available. In addition, there is an effect that the catalyst can be used as an excellent and stable catalyst capable of maintaining a high conversion rate for a relatively long time without shape-selective and deactivation in molecular conversion reaction.
机译:本发明涉及一种中孔微孔板状丝光沸石的生产方法和由此生产的中孔微球状板状丝光沸石,特别是涉及一种SiO 2 / Al摩尔比的丝光沸石前体。 2 O 3 的制造步骤为25至35 A(步骤1);将步骤1的丝光沸石前体与铸模混合(步骤2);在步骤2(步骤3)的混合溶液中结晶丝光沸石;然后,对步骤3的结晶化混合溶液进行热处理以除去流延体(4)的步骤(4),以及中微球状板状丝光沸石的制造方法。本发明可以通过简单的方法制造与板状的中微孔同时的板状的丝光沸石。此时,由于使用廉价的表面活性剂或亲水性聚合物,并且不添加有机硅烷,因此可商购获得,因此可以经济地提供。另外,具有这样的效果,该催化剂可以用作能够在相对长的时间内保持高转化率而在分子转化反应中不发生形状选择和失活的优异且稳定的催化剂。

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