首页> 外国专利> ORGANIC-INORGANIC NANO HYBRID COATING AGENT AND RESIN CONTAINING SILICA PARTICLES SURFACE-MODIFIED WITH OLIGOMER, AND MANUFACTURING METHOD THEREOF

ORGANIC-INORGANIC NANO HYBRID COATING AGENT AND RESIN CONTAINING SILICA PARTICLES SURFACE-MODIFIED WITH OLIGOMER, AND MANUFACTURING METHOD THEREOF

机译:含低聚物改性的二氧化硅颗粒的有机无机纳米杂化涂料剂及其制备方法

摘要

The present invention provides organic-inorganic nano hybrid coating agent and resin comprising silica nanoparticles of which surfaces are modified with oligomer, and preparation methods thereof. A preparation method of an organic-inorganic nano hybrid coating agent comprising silica nanoparticles of which surfaces are modified with oligomer according to the present invention includes: a step of preparing an oligomer comprising nitrogen elements; a step of mixing and stirring the oligomer with silica of which the surface is treated through silane to prepare silica nanoparticles of which surfaces are modified with the oligomer; and a step of mixing the silica nanoparticles of which surfaces are modified with the oligomer with a polymer comprising nitrogen elements. The organic-inorganic nano hybrid coating agent comprising silica nanoparticles of which surfaces are modified with oligomer prepared by the preparation method, provides an effect that is capable of improving adhesive properties, strength, and electrical properties by chain entanglement between the oligomer and the polymer. Further, the organic-inorganic nano hybrid coating agent comprising silica nanoparticles of which surfaces are modified with oligomer of the present invention, provides effects that storage properties of silica sol and a mixed polymer are improved by steric repulsion between oligomers, and the organic-inorganic nano hybrid coating agent can be prepared through a simple condensation process without a separate process.
机译:本发明提供了有机-无机纳米杂化涂布剂和包含其表面被低聚物改性的二氧化硅纳米粒子的树脂及其制备方法。根据本发明的包含表面被低聚物改性的二氧化硅纳米粒子的有机-无机纳米杂化涂层剂的制备方法包括:制备包含氮元素的低聚物的步骤;将低聚物与通过硅烷处理了表面的二氧化硅混合并搅拌的步骤,以制备表面用低聚物改性的二氧化硅纳米颗粒;以及将表面被低聚物改性的二氧化硅纳米粒子与包含氮元素的聚合物混合的步骤。包含通过制备方法制备的低聚物对表面进行了表面改性的二氧化硅纳米粒子的有机-无机纳米杂化涂层剂具有通过低聚物与聚合物之间的链缠结而能够改善粘合性,强度和电特性的效果。此外,包含其表面用本发明的低聚物改性的二氧化硅纳米粒子的有机-无机纳米杂化涂布剂提供了以下效果:通过低聚物之间的空间排斥,改善了二氧化硅溶胶和混合聚合物的储藏性能,并且有机-无机纳米杂化涂层剂可以通过简单的缩合工艺制备而无需单独的工艺。

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