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HIGH FUNCTIONAL COMPLEX POLYESTER POLYOLS

机译:高功能复合聚酯树脂

摘要

1. Highly functional, moderate-viscosity, aromatic polyester polyol substantially free of polyether polyol, suitable for use as the sole polyol in the production of polyurethane foams, which are classified as class one in the tunnel test for fire resistance E-84, wherein said aromatic polyester polyol characterized by functionality in the range from 2.8 to 3.2 and moderate viscosity in the range of 4000-10000 cps at 25 ° C, inclusive, where liol is obtained by transesterification or esterification of a mixture containing: 34-66% (w / w) glycols, 24-34% (w / w) source of terephthalate, 0-17% (w / w) glycerol, 0-14% (w / w) pentaerythritol, 0-5% (w / w) methyl glucoside, 0-10% (w / w) sorbitol, 0-15% (w / w) .) natural vegetable oil, modified natural vegetable oil or fatty acid derivatives of vegetable oil. 2. The aromatic polyester polyol of Claim 1, wherein the glycol is ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, tetrapropylene glycol or polypropylene glycol. 3. The aromatic polyester polyol according to claim 1, wherein the terephthalate source is polyethylene terephthalate (PET), industrial recycled PET, PET after use of the product, terephthalic acid (TA), industrial recycled TA (BACA), phthalic anhydride, isophthalic acid or metaphthalic acid .four. Aromatic complex polyester polyol according to claim 1, where the natural vegetable oil is castor
机译:1.基本上不含聚醚多元醇的高官能度,中等粘度的芳族聚酯多元醇,适合用作聚氨酯泡沫塑料的唯一多元醇,在E-84耐火隧道试验中被列为第一类,其中所述芳族聚酯多元醇,其特征在于在25°C(含)下的官能度在2.8至3.2范围内,中等粘度在4000-10000 cps范围内,其中通过对含有以下成分的混合物进行酯交换或酯化反应制得Liol: w / w)乙二醇,24-34%(w / w)对苯二甲酸酯源,0-17%(w / w)甘油,0-14%(w / w)季戊四醇,0-5%(w / w)甲基葡萄糖苷,0-10%(w / w)山梨糖醇,0-15%(w / w)。)天然植物油,改性天然植物油或植物油的脂肪酸衍生物。 2.权利要求1的芳族聚酯多元醇,其中所述二醇是乙二醇,二甘醇,三甘醇,四甘醇,聚乙二醇,丙二醇,二丙二醇,三丙二醇,四丙二醇或聚丙二醇。 3.根据权利要求1的芳族聚酯多元醇,其中所述对苯二甲酸酯源是聚对苯二甲酸乙二醇酯(PET),工业再生PET,产品使用后的PET,对苯二甲酸(TA),工业再生TA(BACA),邻苯二甲酸酐,间苯二甲酸酸或间苯二甲酸4。 2.根据权利要求1的芳族复合聚酯多元醇,其中天然植物油为蓖麻油

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