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Time-resolved spectrometer and method for time-resolved acquisition of a spectrum of a sample

机译:时间分辨光谱仪和时间分辨采集样品光谱的方法

摘要

The present invention relates to a spectrometer (1, 1 ') for the time-resolved detection of a spectrum of a sample. In order to provide a spectrometer based on a wavelength-time conversion with an improved sampling rate, a spectrometer according to the invention is proposed with a first source (6, 6 ') for generating electromagnetic radiation, a sample holder (7) arranged such that a in the sample holder (7) recorded sample in a beam path of the first source (6, 6 ') in the operation of the spectrometer (1, 1') generated electromagnetic radiation, a second source (2) for generating an electromagnetic pulse, a first group-velocity-dispersive element (3) in a beam path of the electromagnetic pulse generated by the second source (2) in operation of the spectrometer (1, 1 '), a non-linear optical element (9) in the beam path of the electromagnetic radiation of the first source (6, 6 ') behind the sample holder (7) and in the beam path of the electromagnetic pulse from the second Q uelle (2) behind the first group-velocity dispersive element (3) is arranged such that the beam paths in the non-linear optical element (9) spatially overlap, wherein in the operation of the spectrometer (1, 1 '), the electromagnetic radiation from the first Source (6, 6 ') and the electromagnetic pulse from the second source (2) as pump radiation and as signal radiation in the non-linear optical element (9) by four-wave mixing generate an Idler radiation, a detector for the idler Radiation and a detection device electrically connected to the detector, which is set up in such a way that, during operation of the spectrometer (1, 1 '), it records the power of the idler radiation striking the detector in a time-resolved manner.
机译:本发明涉及用于时间分辨地检测样品的光谱的光谱仪(1、1')。为了提供一种基于波长-时间转换的光谱仪,并具有改进的采样率,提出了根据本发明的光谱仪,其具有用于产生电磁辐射的第一源(6、6'),样品架(7)设置为在光谱仪(1、1')的操作中,样品架(7)中的a在第一源(6,6')的光路中记录了样品,第二源(2)用于产生电磁脉冲,在光谱仪(1、1')的操作中由第二源(2)产生的电磁脉冲的光路中的第一组速度色散元件(3),非线性光学元件(9) )在样品架(7)后面的第一源(6,6')的电磁辐射的光路中以及在第一组速度色散之后的第二Qelle(2)的电磁脉冲的光路中布置元件(3),使得非线性光学系统中的光路校准元件(9)在空间上重叠,其中在光谱仪(1、1')的操作中,来自第一源(6、6')的电磁辐射和来自第二源(2)的电磁脉冲作为泵浦辐射和当非线性光学元件(9)中的信号辐射通过四波混合产生一个惰轮辐射时,用于惰轮辐射的检测器和与该检测器电连接的检测设备被设置为在在光谱仪(1、1')的操作中,它以时间分辨的方式记录惰轮辐射撞击检测器的功率。

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