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METAL-BORIDE, METAL-NANOPARTICLES CONTAINED WITH STRITTED METAL-BORIDE AND BORUS FOR WATER-DISSIPATION AND OXYGEN-REDUCTION

机译:金属硼化物,含金属硼化物和氧化硼的金属纳米颗粒,用于耗水和减氧

摘要

The invention relates to metal borides and nitrogen-doped borides of metal (such as cobalt, iron and nickel as metals) with a high surface area and traces of boron-containing metal nanoparticles (such as iridium and ruthenium nanoparticles) with a large surface, their preparation by chemical reduction of the corresponding Sodium borohydride metal salts in an aqueous solution under oxygen-free conditions, catalysts containing such metal borides, nitrogen-doped metal borides or boron-containing metal nanoparticles, and the use of metal borides, nitrogen-doped metal borides, boron-containing metal nanoparticles, and catalysts for catalysing water oxidation under oxygen evolution and in the case of the nitrogen-doped metal borides also for the oxygen reduction and hydrogen evolution.
机译:本发明涉及具有高表面积的金属(例如钴,铁和镍作为金属)的金属硼化物和氮掺杂硼化物以及具有大表面的痕量含硼金属纳米粒子(例如铱和钌纳米粒子),通过在无氧条件下在水溶液中化学还原相应的硼氢化钠金属盐,含有此类金属硼化物,氮掺杂的金属硼化物或含硼金属纳米粒子的催化剂以及使用氮掺杂的金属硼化物来制备它们金属硼化物,含硼金属纳米粒子,以及在放氧条件下催化水氧化的催化剂,在掺氮金属硼化物的情况下,还用于氧还原和放氢。

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