首页> 外国专利> PROCESS FOR THE PREPARATION OF A COLLOIDAL SOLUTION OF NANOPARTICLES OF A VANADIUM AND EUROPIUM MIXED OXIDE OR A MIXED OXIDE OF VANADIUM, EUROPIUM AND YTTRIUM, AND USES THEREOF

PROCESS FOR THE PREPARATION OF A COLLOIDAL SOLUTION OF NANOPARTICLES OF A VANADIUM AND EUROPIUM MIXED OXIDE OR A MIXED OXIDE OF VANADIUM, EUROPIUM AND YTTRIUM, AND USES THEREOF

机译:钒和EURO的混合氧化物或钒,EURO和钇的混合氧化物的纳米颗粒的胶体溶液的制备方法及其用途

摘要

The invention relates to a process for preparing a colloidal solution S2 of nanoparticles of a mixed oxide of formula YxEu1-xVO4 in which x is such that 0 ≤ x 1, which comprises: a) the formation of a S1 colloidal solution by reaction, in an aqueous or aqueous-alcoholic medium, of a precursor P1 of vanadium oxide with a precursor P2 of europium oxide if x = 0, or with a precursor P2 of oxide of europium and a precursor P3 of yttrium oxide if x ≠ 0, the reaction being obtained by fractional addition of P2 or P2 and P3 to a solution comprising P1, or by fractional addition of P1 to a solution comprising P2 or P2 and P3; and b) curing the colloidal solution S1 formed in step a); and which is characterized in that: 1 °) step a) comprises a regulation of the pH of the medium in which the precursors of metal oxides react with each other; and in that 2 °) step b) comprises heating the colloidal solution S1 in a microwave oven. The invention also relates to the uses of the colloidal solution thus obtained. Applications: detection by a fluorescence optical sensor of target molecules present in a gaseous or liquid medium, in particular peroxides such as hydrogen peroxide.
机译:本发明涉及一种制备式YxEu1-xVO4的混合氧化物的纳米粒子的胶体溶液S2的方法,其中x为0≤x<1,其包括:a)通过反应形成S1胶体溶液,在水或水-醇介质中,如果x = 0,则氧化钒的前体P1与氧化oxide的前体P2,如果x≠0,则具有euro的氧化物的前体P2和氧化钇的前体P3,通过将P2或P2和P3分批添加到包含P1的溶液中,或通过将P1分批添加到包含P2或P2和P3的溶液中来获得反应。 b)固化步骤a)中形成的胶体溶液S1;并且其特征在于:1°)步骤a)包括调节金属氧化物的前体在其中彼此反应的介质的pH;并且在2°)中,步骤b)包括在微波炉中加热胶体溶液S1。本发明还涉及由此获得的胶体溶液的用途。应用:通过荧光光学传感器检测气态或液态介质中存在的目标分子,特别是过氧化物,例如过氧化氢。

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