首页> 外国专利> Catalytic cracking method suitable for processing feedstocks with low Conradson carbon residue, which comprises recycling a coking cut according to a novel technology

Catalytic cracking method suitable for processing feedstocks with low Conradson carbon residue, which comprises recycling a coking cut according to a novel technology

机译:适用于处理低康拉逊碳残渣原料的催化裂化方法,该方法包括根据新技术回收焦化馏分

摘要

The process comprises introducing a coked catalyst in an outlet of a main reactor (1) into a stripper operating in fluidized bed and having a dense phase topped with a dilute phase (2), and recycling cuts of light cycle oil, heavy cycle oil and/or slurry using coking cut in a fluidized lateral capacity placed in derivation of stripper and along a transfer line. A catalytic cracking unit has Conradson carbon of less than 0.1 and hydrogen content of greater than 12.7 wt.%. An upper portion of the transfer line has its origin at an upper point that is greater than the dense phase of stripper. The process comprises introducing a coked catalyst in an outlet of a main reactor (1) into a stripper operating in fluidized bed and having a dense phase topped with a dilute phase (2), and recycling cuts of light cycle oil, heavy cycle oil and/or slurry using coking cut in a fluidized lateral capacity placed in derivation of stripper and along a transfer line. A catalytic cracking unit has Conradson carbon of less than 0.1 and hydrogen content of greater than 12.7 wt.%. An upper portion of the transfer line has its origin at an upper point that is greater than the dense phase of stripper. A lower portion of the transfer line has its return to the dense phase of the stripper at a point below the upper point. The lateral capacity is placed upstream of a control valve of the flow rate of catalyst, is placed on the lower portion of the transfer line, is provided with a vent line for the return of the gas products in the dilute phase of the stripper, and comprises a lower packing placed in its lower part and located below the point of introduction of the recycle stream, and a higher packing placed in its upper part and located above the point of introduction of the catalyst by the transfer line. The flow of extraction of the catalyst introduced into the lateral capacity is 50-100 kg/m 2/s. The residence time of the overall catalyst in the lateral capacity is 20-100 seconds. The catalyst taken from the dense phase of the stripper and brought into the lateral capacity is introduced into the dilute phase of the enclosure using a dispersion device. The coking cut is made within a tubular enclosure placed inside the stripper. An upper end of the enclosure opens into the dilute phase of the stripper, and the lower end of the enclosure opens into the dense phase of the stripper. The tubular enclosure is positioned so that the part immersed in the dense phase of the stripper is 30-100% of the total length of the tubular enclosure. A secondary reactor operates in parallel of the main reactor and works in operating conditions that is more stringent than the main reactor, and treats by mixing 4-5C olefinic cut and gasoline cut and/or recycled C5, C6, C7 or C8 oligomerat. An outlet temperature of the main reactor is 500-560[deg] C and C/O ratio is 5-10. An outlet temperature of the secondary reactor is 580-610[deg] C and the contact time is 50-200 ms. The recycled coking cut contains an external cut at the catalytic cracking unit type of wood or cellulose biomass, liquid hydrocarbon product from oil, pulverized coal, rich cut asphalt from a deasphalting unit, wax from a unit of indirect coal liquefaction, petroleum coke or a mixture of the fractions.
机译:该方法包括在主反应器(1)的出口中将焦化的催化剂引入在流化床中操作的汽提器中,该汽提器的密相顶上是稀相(2),并且将轻循环油,重循环油和/或使用焦化的浆料将流化的侧向容量切成在汽提塔中并沿传输线放置。催化裂化单元的Conradson碳小于0.1,氢含量大于12.7 wt。%。传输线的上部的起始点大于汽提塔的密相。该方法包括在主反应器(1)的出口中将焦化的催化剂引入在流化床中操作的汽提器中,该汽提器的密相顶上是稀相(2),并且将轻循环油,重循环油和/或使用焦化的浆料将流化的侧向容量切成汽提塔并沿传输线放置。催化裂化单元的Conradson碳小于0.1,氢含量大于12.7 wt。%。传输线的上部的起始点大于汽提塔的密相。传输线的下部在上点以下的点返回到汽提塔的密相。横向容量位于催化剂流量控制阀的上游,位于输送管线的下部,设有排气管线,用于使汽提塔稀相中的气体产物返回,并且包括位于其下部并位于再循环料流引入点下方的下部填料,以及置于其上部并经转移管线位于催化剂引入点上方的上部填料。引入横向容量的催化剂的提取流量为50-100kg / m 2> / s。整个催化剂在横向容量中的停留时间为20-100秒。使用分散装置将从汽提塔的密相中提取并带入侧向容量的催化剂引入到外壳的稀相中。焦化切口在置于汽提塔内的管状外壳内进行。外壳的上端通向汽提塔的稀相,而外壳的下端通向汽提塔的密相。放置管状外壳的位置应使浸入汽提塔密相中的部分占管状外壳总长度的30-100%。二级反应器与主反应器平行运行,并在比主反应器更严格的操作条件下工作,并通过混合4-5C烯烃馏分和汽油馏分和/或循环使用的C5,C6,C7或C8低聚物进行处理。主反应器的出口温度为500-560℃,C / O比为5-10。二级反应器的出口温度为580-610℃,接触时间为50-200ms。回收的焦炭馏分包括在催化裂化单元类型的木材或纤维素生物质的外部馏分,石油,粉煤的液态烃产品,脱沥青单元的富馏分沥青,间接煤液化单元的蜡,石油焦或各部分的混合物。

著录项

  • 公开/公告号EP2441816B1

    专利类型

  • 公开/公告日2017-03-29

    原文格式PDF

  • 申请/专利权人 IFP ÉNERGIES NOUVELLES;

    申请/专利号EP20110290420

  • 发明设计人 ROUX ROMAIN;FEUGNET FREDERIC;

    申请日2011-09-19

  • 分类号C10G11/18;

  • 国家 EP

  • 入库时间 2022-08-21 14:06:32

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