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PERMANENT REFERENCE ELETRODE FOR THE POTENTIAL MEASUREMENT OF BURIED METALLIC STRUCTURES

机译:永久参考电极用于潜伏金属结构的电位测量

摘要

A permanent reference electrode (10, 10-1) for the potential measurement of buried metallic structures (ST) in order to verify their state of corrosion or cathodic protection including:- a zinc element or electrode (11) of elongated shape;- a special filling material (12) or backfill, based on gypsum, bentonite, cellulose fibre, sodium chloride and water, surrounding the zinc electrode (11);- a containment body (13) created around the backfill (12) and made of cementitious mortar (13') enriched with chloride ions; and- an external element or case (14), made of plastic material, that covers the cementitious containment body (13) and serve as the electrode case (10);where the cementitious mortar (13') of the containment body (13), in a respective area left uncovered by the outer casing (14), constitute the electrolyte contact with the ground (T) where the zinc reference electrode (10, 10-1) is buried, in a permanent way in proximity of the buried metallic structures (ST), of which the electrochemical potential is measured compared to the same reference electrode (10, 10-1).;In a further form of realization (10, 10-2) the zinc reference electrode does not include the cementitious containment body, but only the backfill (12) and a porous separator (19) adjacent to the last one, having a porosity likely to realize the electrolyte contact with the ground (T) where the reference electrode (10-2) is buried.;The zinc permanent reference electrode (10, 101-1; 10-2) of the invention is usefully likely to remain active for a long period of time in soil (T) where is buried and not to be subjected to the passivation phenomenon.
机译:永久性参比电极(10、10-1),用于测量埋入式金属结构(ST)的电势,以验证其腐蚀或阴极保护状态,包括:-细长的锌元素或电极(11);-围绕锌电极(11)的一种特殊填充材料(12)或回填材料,基于石膏,膨润土,纤维素纤维,氯化钠和水;-在回填物(12)周围形成的密封体(13),由富含氯离子的水泥砂浆(13')制成;和-由塑料制成的外部元件或壳体(14),其覆盖水泥质容纳体(13)并用作电极壳体(10);其中,在未由外壳(14)覆盖的各个区域中,容纳体(13)的胶结砂浆(13')构成了与地面(T)的电解质接触,锌参比电极(10、10- 1)以永久的方式埋入埋入的金属结构(ST)附近,与同一参考电极(10,10-1)相比,测量其电化学势。;以另一种实现方式(10) ,10-2)锌参比电极不包括胶结容器,而仅包括回填(12)和与最后一个相邻的多孔隔板(19),其孔隙率可能使电解质与地面接触( T)埋在参考电极(10-2)中;本发明的锌永久参考电极(10,101-1; 10-2)很有可能在土壤(T中)长期保持活性)被掩埋且不遭受钝化现象的地方。

著录项

  • 公开/公告号EP3101411A1

    专利类型

  • 公开/公告日2016-12-07

    原文格式PDF

  • 申请/专利权人 CESCOR S.R.L.;

    申请/专利号EP20160172305

  • 申请日2016-05-31

  • 分类号G01N17/02;C23F13/06;

  • 国家 EP

  • 入库时间 2022-08-21 14:02:04

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