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NICKEL POWDER, PRODUCTION METHOD OF NICKEL POWDER, INNER ELECTRODE PASTE USING NICKEL POWDER, AND ELECTRONIC COMPONENT

机译:镍粉,镍粉的生产方法,使用镍粉的内电极浆料和电子成分

摘要

PROBLEM TO BE SOLVED: To provide nickel powder used for an inner electrode paste for electronic components and obtained by a wet method, which is fine nickel powder having high crystallinity and excellent sintering characteristics and thermal shrinkage characteristics.SOLUTION: There is provided a method for obtaining crystallized powder of nickel by precipitating nickel with a reduction reaction. The production method comprises: preparing a rection solution by mixing a nickel salt solution containing a water-soluble nickel salt and a metal salt of a metal nobler than nickel, and a mixed reductant solution containing hydrazine and an alkali metal hydroxide; after a reduction reaction has started in the reaction solution, further adding the hydrazine additionally to the reaction solution so that a total amount of the initial hydrazine added to the mixed reductant solution and the hydrazine additionally added to the reaction solution becomes a predetermined amount. The nickel powder has roughly a spherical particle shape, an average particle size of 0.05 to 0.5 μm, an average crystallite diameter of 30 to 80 nm, a nitrogen content of 0.02 mass% or less, and an alkali metal element content of 0.01 mass% or less.SELECTED DRAWING: Figure 1
机译:解决的问题:提供一种通过湿法获得的,用于电子部件内部电极浆料的镍粉,它是具有高结晶度,优良的烧结特性和热收缩特性的精细镍粉。通过还原反应使镍沉淀,得到结晶的镍粉末。该制造方法包括:通过将包含水溶性镍盐和比镍贵金属的金属盐的镍盐溶液与包含肼和碱金属氢氧化物的混合还原剂溶液混合来制备反应溶液;在反应溶液中开始还原反应后,进一步向反应溶液中另外添加肼,以使得添加到混合还原剂溶液中的初始肼和另外添加到反应溶液中的肼的总量变为预定量。镍粉具有大致球形的颗粒形状,平均粒径为0.05至0.5μm,平均微晶直径为30至80nm,氮含量为0.02质量%以下,碱金属元素含量为0.01质量%。或更少。选定的图纸:图1

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