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Metallocene compound, catalyst containing the same, process for producing olefin polymer using the catalyst, and olefin homopolymer and copolymer

机译:茂金属化合物,包含该茂金属化合物的催化剂,使用该催化剂生产烯烃聚合物的方法以及烯烃均聚物和共聚物

摘要

PROBLEM TO BE SOLVED: To solve shortcomings of metallocene compounds of the present technology standard and to provide metallocenes that increase desirable characteristics such as high melting point, high molar mass homopolymers and high molar mass copolymers, and do so at higher productivities when used as components of supported catalysts under industrially relevant polymerization conditions at temperatures of from 50 to 100°C.SOLUTION: Certain metallocene compounds are provided that, when used as a component in a supported polymerization catalyst under industrially relevant polymerization conditions, afford high molar mass homo polymers or copolymers like polypropylene or propylene/ethylene copolymers without the need for any α-branched substituent in either of the two available 2-positions of the indenyl ligands.
机译:要解决的问题:解决本技术标准的茂金属化合物的缺点,并提供能够增加所需特性(例如高熔点,高摩尔质量均聚物和高摩尔质量共聚物)的茂金属,并在用作组分时以较高的生产率实现在工业相关的聚合条件下,温度为50至100°C的条件下制备负载型催化剂。解决方案:提供某些茂金属化合物,当在工业相关的聚合条件下用作负载型聚合催化剂的组分时,可提供高摩尔质量的均聚物或共聚物,例如聚丙烯或丙烯/乙烯共聚物,而在茚基配体的两个可用的2-位中的任何一个上都不需要任何α-支链取代基。

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