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Actinides, lanthanides and superabsorbent gels for fission product decontamination

机译:用于裂变产物净化的系元素,镧系元素和超强吸收性凝胶

摘要

The present invention provides an aqueous gel composition for removing actinide ions, lanthanide ions, fission product ions, or a combination thereof from a porous surface contaminated therewith. The composition comprises a polymer mixture comprising a gel forming cross-linked polymer and a linear polymer. The linear polymer is present at a concentration that is less than the concentration of the cross-linked polymer. The polymer mixture is at least about 95% hydrated with an aqueous solution comprising about 0.1 to about 3 percent by weight (wt %) of a multi-dentate organic acid chelating agent, and about 0.02 to about 0.4 molar (M) carbonate salt, to form a gel. When applied to a porous surface contaminated with actinide ions, lanthanide ions, and/or other fission product ions, the aqueous gel absorbs contaminating ions from the surface.
机译:本发明提供了一种水性凝胶组合物,用于从被其污染的多孔表面除去act系元素离子,镧系元素离子,裂变产物离子或其组合。该组合物包含聚合物混合物,该聚合物混合物包括形成凝胶的交联聚合物和线性聚合物。线性聚合物的存在浓度小于交联聚合物的浓度。所述聚合物混合物用包含约0.1至约3重量%(wt%)的多齿有机酸螯合剂和约0.02至约0.4摩尔(M)碳酸盐的水溶液水合至少约95%,形成凝胶。当施加到被act系元素离子,镧系元素离子和/或其他裂变产物离子污染的多孔表面上时,水性凝胶从表面吸收污染离子。

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