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Polychloroprene latex, polychloroprene latex composition and molded article

机译:聚氯丁二烯胶乳,聚氯丁二烯胶乳组合物和模制品

摘要

An object of the present invention is to provide a polychloroprene latex with improved rubber coagulability that gives a film superior in strength by dip molding, a polychloroprene latex composition, and a molded article. The polychloroprene latex is prepared by polymerization of 2-chloro-1,3-butadiene alone or by polymerization of raw monomers at least containing 2-chloro-1,3-butadiene and 2,3-dichloro1,3-butadiene and has a precipitation rate of 5 to 40%, as calculated according to Equation (I). In Equation (I), A is the mass (g) of the dry product, which is obtained by adding 50 ml of saturated aqueous solution of calcium hydroxide at 23°C to 50 g of a latex having a solid matter concentration adjusted to 45 to 65 mass % at a liquid temperature of 23°C over 2 minutes, filtering and collecting the generated precipitate with a 80-mesh wire mesh, and drying the precipitate at 110°C for 3 hours; B is the mass of the latex before the dropwise addition (50 g); and C is the solid matter concentration (mass %) of the latex before the dropwise addition. Precipitation rate % = A B × C 100 × 100
机译:本发明的目的是提供一种具有改善的橡胶凝集性的聚氯丁二烯胶乳,聚氯丁二烯胶乳组合物和模制品,所述聚氯丁二烯胶乳通过浸渍模塑得到强度优异的膜。聚氯丁二烯胶乳是通过单独聚合2-氯-1,3-丁二烯或通过聚合至少含有2-氯-1,3-丁二烯和2,3-二氯1,3-丁二烯的粗单体而制备的,并具有沉淀作用根据公式(I)计算得出的比率为5%至40%。在式(I)中,A是干燥产物的质量(g),其通过将50ml在23℃下的饱和氢氧化钙水溶液添加到50g固体物质浓度被调节为45的胶乳中而获得。在2分钟的液体温度下于23℃达到65质量%,用80目的金属丝网过滤并收集所产生的沉淀物,并在110℃下干燥沉淀物3小时。 B是滴加前乳胶的质量(50g); C为滴加前的乳胶的固体成分浓度(质量%)。沉淀率%= A B×C 100×100

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