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Photosensitive composition for volume hologram recording, photosensitive substrate for volume hologram recording, and volume hologram recording body

机译:用于体积全息图记录的光敏组合物,用于体积全息图记录的光敏基板和体积全息图记录体

摘要

The present invention is to provide: a photosensitive composition for volume hologram recording and a photosensitive substrate for volume hologram recording, which provide increased sensitivity during hologram recording and a high refractive index modulation amount, and which do not inhibit the decolorization of the sensitizing dye; and a volume hologram recorded medium which provides high-luminance hologram images with increased productivity. Disclosed is a photosensitive composition for volume hologram recording, comprising: a photopolymerizable monomer, a photopolymerization initiator, a sensitizing dye for sensitizing the photopolymerization initiator, a binder resin, and a thiol group-containing compound, wherein the photopolymerizable monomer contains a photoradically polymerizable monomer and a photocationically polymerizable monomer; wherein the thiol group-containing compound is a chain transfer agent for the photoradically polymerizable monomer and is a polyfunctional secondary thiol compound having two or more secondary thiol groups per molecule; and wherein the content of the thiol group-containing compound is 1.5 to 30 parts by mass with respect to 100 parts by mass of the photoradically polymerizable monomer.
机译:本发明提供:用于体积全息图记录的光敏组合物和用于体积全息图记录的光敏基板,其在全息图记录期间提供增加的灵敏度和高折射率调制量,并且不抑制敏化染料的脱色。以及体积全息图记录介质,其提供具有提高的生产率的高亮度全息图图像。公开了一种用于体积全息图记录的光敏组合物,其包含:光聚合性单体,光聚合引发剂,用于使光聚合引发剂敏化的敏化染料,粘合剂树脂和含硫醇基的化合物,其中所述光聚合性单体包含光自由基聚合性单体。和光阳离子聚合性单体;其中含硫醇基的化合物是光自由基聚合单体的链转移剂,并且是每分子具有两个或更多个仲硫醇基的多官能仲硫醇化合物。相对于100质量份光自由基聚合性单体,所述含硫醇基化合物的含量为1.5〜30质量份。

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