A photopolymerizable liquid crystal composition capable of forming a positive A plate having improved wavelength dispersion characteristics of birefringence and good heat resistance to the manufacturing process of a liquid crystal display device, an optical compensation film using the same, an optical compensation laminate A film, an electrode substrate, a substrate for a liquid crystal display device, and a liquid crystal display device are provided. (A) for forming an optical compensation film exhibiting positive uniaxial anisotropy, comprising a first photopolymerizable liquid crystal (A) having an aliphatic ring and not having an aromatic ring, and a second And a photopolymerizable liquid crystal (B), wherein the amount of the first photopolymerizable liquid crystal (A) is 50% by mass or more and less than 100% by mass with respect to the total amount of the photopolymerizable liquid crystal, and the second photopolymerization And the amount of the liquid crystal (B) is from more than 0% by mass to 50% by mass or less. The optical compensation laminated film 12 includes an optical compensation film 12 A exhibiting negative uniaxial anisotropy and an optical compensation film 12 B having positive uniaxial anisotropy produced using the above composition.
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