首页> 外国专利> EFFICIENT PRODUCTION OF COMPOSITE SEMIFINISHED PRODUCTS AND COMPONENTS IN A WET PRESSING METHOD USING HYDROXY FUNCTIONALIZED (METH)ACRYLATES WHICH ARE DUROPLASTICALLY CROSSLINKED USING ISOCYANATES OR URETDIONES

EFFICIENT PRODUCTION OF COMPOSITE SEMIFINISHED PRODUCTS AND COMPONENTS IN A WET PRESSING METHOD USING HYDROXY FUNCTIONALIZED (METH)ACRYLATES WHICH ARE DUROPLASTICALLY CROSSLINKED USING ISOCYANATES OR URETDIONES

机译:使用羟基官能化(甲基)丙烯酸酯通过异氰脲酸酯或脲基甲酸酯进行交联交联的湿式压制方法,可高效生产复合半成品和组件

摘要

The invention relates to a process for producing semi-finished composites and composite components. For production of the semi-finished products or components, (meth)acrylate monomers, (meth)acrylate polymers, polyfunctionalized (meth)acrylates, hydroxy-functionalized (meth)acrylate monomers and/or hydroxy-functionalized (meth)acrylate polymers are mixed with di- or polyisocyanates or with uretdione materials. This liquid mixture is applied by known processes to fibre material, for example carbon fibres, glass fibres or polymer fibres, and polymerized with the aid of a first temperature increase or of a redox accelerator or by means of photoinitiation. Polymerization, for example at room temperature or at up to 120° C., gives rise to thermoplastics which can still be subjected to a forming operation. The hydroxy-functionalized (meth)acrylate constituents can subsequently be crosslinked in a press with isocyanates or uretdiones already present in the system at a second temperature at least 20° C. above the polymerization temperature. In this case, the shaping to give the final component is effected simultaneously in this press. In this way, dimensionally stable thermosets or crosslinked composite components can be produced.
机译:本发明涉及一种用于生产半成品复合材料和复合部件的方法。为了生产半成品或组分,将(甲基)丙烯酸酯单体,(甲基)丙烯酸酯聚合物,多官能化的(甲基)丙烯酸酯,羟基官能化的(甲基)丙烯酸酯单体和/或羟基官能化的(甲基)丙烯酸酯聚合物混合。与二异氰酸酯或多异氰酸酯或脲二酮材料一起使用。通过已知的方法将该液体混合物施加到纤维材料上,例如碳纤维,玻璃纤维或聚合物纤维,并借助于第一温度升高或氧化还原促进剂或通过光引发聚合。例如在室温或高达120℃下的聚合产生了仍可经受成型操作的热塑性塑料。羟基官能化的(甲基)丙烯酸酯成分随后可以在压机中与系统中已经存在的异氰酸酯或脲二酮在高于聚合温度至少20℃的第二温度下交联。在这种情况下,在该压机中同时进行赋予最终成分的成型。以这种方式,可以生产尺寸稳定的热固性或交联的复合部件。

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