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Ultra-thin, Pinhole-free, Flexible Metal-Organic Films
Ultra-thin, Pinhole-free, Flexible Metal-Organic Films
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机译:超薄,无针孔,柔性金属有机薄膜
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摘要
Described herein are facile, one-step initiated plasma enhanced chemical vapor deposition (iPECVD) methods of synthesizing hyper-thin (e.g., sub-100 nm) and flexible metal organic covalent network (MOCN) layers. As an example, the MOCN may be made from zinc tetraphenylporphyrin (ZnTPP) building units. When deposited on a membrane support, the MOCN layers demonstrate gas separation exceeding the upper bounds for multiple gas pairs while reducing the flux as compared to the support alone.
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