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Disentangled high or ultrahigh molecular weight polyethylene prepared with Ziegler-Natta catalyst
Disentangled high or ultrahigh molecular weight polyethylene prepared with Ziegler-Natta catalyst
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机译:用齐格勒-纳塔催化剂制备的高分子量或超高分子量聚乙烯
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摘要
Disentangled high or ultrahigh molecular weight polyethylene ((U)HMWPE) being produced with a Ziegler-Natta catalyst, characterized by (i) a factor for the normalized elastic modulus G′0/G′P of less than 0.95 determined in a dynamic time sweep measurement at 180° C. with constant strain of 0.5% at fixed frequency of 10 rad/s for at least 3600 s, whereby G′0 is the elastic shear modulus measured at t0 directly after melting the sample and G′p is the maximum plateau modulus.
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机译:用齐格勒-纳塔催化剂生产的高分子量或超高分子量聚乙烯(U)HMWPE,其特征在于(i)归一化弹性模量G' 0 Sub> / G'的因子P Sub>小于0.95,是在180°C的动态时间扫描测量中以0.5%的恒定应变在10 rad / s的固定频率下至少3600 s测得的,从而G' 0 Sub>是样品熔化后在t 0 B>处直接测量的弹性剪切模量,而G' p Sub>是最大平稳模量。
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