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5A molecular sieve adsorbent and method for preparation of the same

机译:5A分子筛吸附剂及其制备方法

摘要

The present invention provides an adsorbent and a method for preparation of the adsorbent, wherein, the average crystal grain diameter of 5A molecular sieves in the adsorbent is 0.2-2.1 μm; measured on the basis of the dry weight of the adsorbent, the content of 5A molecular sieves in the adsorbent is 92 wt. % or higher; the breaking ratio of the adsorbent at 250N is 9% or lower. The method for preparation of the adsorbent comprises: processing a powder material that contains 4A molecular sieves and a binder source by roll forming to obtain beads; drying and calcining the beads to obtain matrix beads; pre-wetting the matrix beads and then processing the matrix beads by crystal transformation so that the binder in the matrix beads is essentially transformed into 4A molecular sieves, to obtain 4A molecular sieve beads; washing the 4A molecular sieve beads with water and then processing the 4A molecular sieve beads by calcium exchange to obtain 5A molecular sieve beads; washing the 5A molecular sieve beads with water and then drying and calcining the 5A molecular sieve beads. The adsorbent provided in the present invention has advantages such as high adsorptive capacity and adsorption efficiency for n-alkanes and high strength.
机译:本发明提供了一种吸附剂及其制备方法,其中,所述吸附剂中5A分子筛的平均晶粒直径为0.2〜2.1μm。以吸附剂的干重为基础测量,吸附剂中5A分子筛的含量为92重量%。 % 或更高; 250N时的吸附剂的破坏率为9%以下。制备吸附剂的方法包括:通过辊压加工处理包含4A分子筛和粘合剂源的粉末材料以获得珠粒;和将珠干燥并煅烧以获得基质珠;预润湿基体微珠,然后通过晶体转化处理基体微珠,使基体微珠中的粘合剂基本上转化为4A分子筛,得到4A分子筛微珠。用水洗涤4A分子筛珠,然后通过钙交换处理4A分子筛珠,得到5A分子筛珠。用水洗涤5A分子筛珠,然后干燥并煅烧5A分子筛珠。本发明提供的吸附剂具有诸如对正构烷烃的高吸附能力和吸附效率以及高强度的优点。

著录项

  • 公开/公告号US9656241B2

    专利类型

  • 公开/公告日2017-05-23

    原文格式PDF

  • 申请/专利权人 CHINA PETROLEUM & CHEMICAL CORPORATION;

    申请/专利号US201314064731

  • 发明设计人 YUNLONG DING;SHIHUA CHEN;CHANGZHI TU;

    申请日2013-10-28

  • 分类号B01J29/06;B01J20/18;B01J20/30;B01J29/70;B01J20/28;B01J35/02;B01J37/00;B01J35/10;

  • 国家 US

  • 入库时间 2022-08-21 13:45:09

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