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Process for producing a polymeric material pelotizado expandable material pelotizado expandable molded part, composite molded body, and use of a molded part

机译:聚合物材料pelotizado可膨胀材料的生产方法,pelotizado可膨胀成型部件,复合成型体以及成型部件的用途

摘要

Producing expandable granules, comprises e.g. (i) providing a polymer component comprising (a) a styrene polymer component which is formed from (a1) at least one styrene polymer and (a2) at least one styrene copolymer different from (a1), and (b) at least one thermoplastic polymer, (ii) heating the polymer component to form a polymer melt (iii) introducing a physical blowing agent component into the polymer melt to form a foamable melt, (iv) homogenizing the mixture, and (v) optionally adding additives to the polymer component in at least one of the steps (i), (ii), (iii) and/or (iv). Producing expandable granules, comprises: (i) providing a polymer component comprising (a) a styrene polymer component (90-100 wt.%, based on polymer component), which is formed from ((a1) at least one styrene polymer (30-100 wt.%, based on polymer component), each containing copolymerized styrene, alpha-methyl styrene or copolymerized mixture of alpha-methyl styrene and styrene (60-85 wt.%, based on styrene polymer) and at least one copolymerized monomer (15-40 wt.%, based on styrene polymer) including maleic acid anhydride or maleimide and (a2) at least one styrene copolymer different from (a1) (0-70 wt.%, based on polymer component) including copolymerized styrene, alpha-methyl styrene or the copolymerized mixture of styrene and alpha-methyl styrene (60-82 wt.%, based on styrene copolymer different from (a1)) and copolymerized acrylonitrile (18-40 wt.%, based on styrene copolymer different from (a1)), and (b) at least one thermoplastic polymer (0-10 wt.% based on polymer component) including aromatic polyether, polyolefin, polyacrylate, polycarbonate, polyester, polyamide, polyethersulfone, polyether ketone or polyether sulfide; (ii) heating the polymer component to form a polymer me (iii) introducing a physical blowing agent component (1-10 wt.%, based on polymer component) into the polymer melt to form a foamable me (iv) homogenizing the mixture; (v) optionally adding additives to the polymer component in at least one of the steps (i), (ii), (iii) and/or (iv); (vi) extruding the polymer melt comprising blowing agent through a nozzle plate; and (vii) granulating the melt comprising blowing agent in a liquid-filled chamber under a pressure of 1.5-15 bar to form the granulate. Independent claims are also included for: (1) the expandable granules, whose particles respectively contain at least 10 hollow spaces/mm 3with the size of 1-200 mu m, comprising the polymer component as mentioned above, where the styrene polymer component has a glass transition temperature of = 130[deg] C; and (2) molded parts obtainable from the above produced expandable granulates, which exhibit a density of 15-300 g/l and a maximum dimensional change of 3% upon thermal loading of at least 130[deg] C.
机译:生产可膨胀的颗粒,包括例如(i)提供一种聚合物组分,其包含(a)由(a1)至少一种苯乙烯聚合物和(a2)至少一种不同于(a1)的苯乙烯共聚物和(b)至少一种热塑性塑料形成的苯乙烯聚合物组分。聚合物;(ii)加热聚合物组分以形成聚合物熔体;(iii)将物理发泡剂组分引入聚合物熔体中以形成可发泡的熔体;(iv)均化混合物;以及(v)可选地向聚合物中添加添加剂步骤(i),(ii),(iii)和/或(iv)至少之一中的组分。生产可膨胀的颗粒,包括:(i)提供一种聚合物组分,该聚合物组分包括(a)由((a1)至少一种苯乙烯聚合物(30)形成的苯乙烯聚合物组分(基于聚合物组分为90-100重量%)。 -100 wt。%(基于聚合物组分),每种均包含共聚苯乙烯,α-甲基苯乙烯或α-甲基苯乙烯和苯乙烯的共混混合物(基于苯乙烯聚合物为60-85 wt。%)和至少一种共聚单体(15-40重量%,基于苯乙烯聚合物)包括马来酸酐或马来酰亚胺和(a2)至少一种不同于(a1)的苯乙烯共聚物(0-70重量%,基于聚合物组分),包括共聚苯乙烯, α-甲基苯乙烯或苯乙烯与α-甲基苯乙烯的共聚混合物(60-82 wt。%,基于不同于(a1)的苯乙烯共聚物)和共聚丙烯腈(18-40 wt。%,基于不同于(a1)),和(b)至少一种热塑性聚合物(相对于聚合物组分为0-10 wt。%)包括芳族聚醚,聚烯烃,聚丙烯酸酯,聚碳酸酯,聚酯,聚酰胺,聚醚砜,聚醚酮或聚醚硫化物; (ii)加热聚合物组分以形成聚合物熔体; (iii)将物理发泡剂组分(基于聚合物组分为1-10重量%)引入聚合物熔体中以形成可发泡的熔体; (iv)将混合物均质化; (v)任选地在步骤(i),(ii),(iii)和/或(iv)中的至少一个中将添加剂添加到聚合物组分中; (vi)通过喷嘴板挤出包含发泡剂的聚合物熔体; (vii)在充满液体的室内在1.5-15巴的压力下将包含发泡剂的熔体造粒以形成颗粒。还包括以下独立权利要求:(1)可膨胀颗粒,其颗粒分别包含至少10个中空空间/ mm 3,尺寸为1-200μm,包含上述聚合物组分,其中苯乙烯聚合物组分玻璃化转变温度≥130℃; (2)由上述生产的可膨胀颗粒获得的模制件,在至少130℃的热负荷下,其密度为15-300g / l,最大尺寸变化为3%。

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