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colloidal silicas, process for producing a colloidal silica, use of colloidal silica, and process for producing paper and cardboard

机译:胶体二氧化硅,制备胶体二氧化硅的方法,胶体二氧化硅的用途以及纸和纸板的制备方法

摘要

Colloidal Silicas, Process for Producing a Colloidal Silica, Use of Colloidal Silica, and Process for Making Paper and Cardboard The present invention relates to a colloidal silica having a ph above 10, molar ratio of sio2: m2o, in which m is alkali metal, from about 6: 1 to about 16: 1, soluble silica concentration above about 3000 mg of sodium2 / l, and s value from about 18 to about 40%. The invention further relates to a process for producing a colloidal silica comprising acidifying an aqueous metal silicate solution to a pH from 1 to 4 to form an acid colloid, alkalinizing the acid colloid by adding the silicate solution. aqueous alkali metal to obtain an intermediate colloid and stop the addition of aqueous alkali metal silicate solution when the intermediate colloid has reached a ph from about 5 to about 8, agitation of the intermediate colloid for a period of time from approximately 10 to about 6000 seconds without the addition of aqueous alkali metal silicate solution, alkalization of the intermediate colloid by the addition of aqueous alkali metal silicate solution to obtain a colloidal silica having a ph above about 10 and molar ratio of sio2: m2o, where m is alkali metal, from about 6: 1 to about 16: 1, and optional addition of an aluminum compound to the acid colloid, intermediate colloid or colloidal silica. The invention also relates to a colloidal silica obtainable by the process of the invention. The invention relates to the use of colloidal silica as a flocculating agent, in water purification and in the production of paper and cardboard. The invention further relates to a papermaking process comprising: (i) providing an aqueous suspension comprising cellulosic fibers; (ii) adding to the suspension one or more drainage and retention aids comprising colloidal silica; and (iii) dehydrating the suspension obtained to provide a sheet or mesh of paper or cardboard. 1/2
机译:胶态二氧化硅,胶态二氧化硅的制备方法,胶态二氧化硅的用途以及纸和纸板的制备方法技术领域本发明涉及一种具有ph大于10,sio2:m2o的摩尔比的ph的胶态二氧化硅,其中m是碱金属,在约6∶1至约16∶1的范围内,可溶性二氧化硅的浓度在约3000mg钠2 / l以上,并且s值为约18至约40%。本发明进一步涉及一种制备胶体二氧化硅的方法,该方法包括将金属硅酸盐水溶液酸化至pH为1-4以形成酸胶体,通过添加该硅酸盐溶液来碱化该酸胶体。碱金属水溶液以获得中间胶体,并在中间胶体的pH值达到约5至约8时停止添加碱金属硅酸盐水溶液,将中间胶体搅拌约10至约6000秒在不添加碱金属硅酸盐水溶液的情况下,通过添加碱金属硅酸盐水溶液对中间胶体进行碱化,从而得到pH值大于约10且sio2:m2o(其中m为碱金属)的摩尔比的胶体二氧化硅。约6∶1至约16∶1,以及任选地向酸胶体,中间胶体或胶体二氧化硅中添加铝化合物。本发明还涉及通过本发明的方法可获得的胶体二氧化硅。本发明涉及胶态二氧化硅作为絮凝剂在水净化以及在纸和纸板的生产中的用途。本发明进一步涉及一种造纸方法,其包括:(i)提供包含纤维素纤维的水性悬浮液; (ii)向悬浮液中添加一种或多种包含胶体二氧化硅的助滤助留剂; (iii)使获得的悬浮液脱水以提供纸或纸板的片或网。 1/2

著录项

  • 公开/公告号BR112016002353A2

    专利类型

  • 公开/公告日2017-08-01

    原文格式PDF

  • 申请/专利权人 AKZO NOBEL CHEMICALS INTERNATIONAL B.V.;

    申请/专利号BR20161102353

  • 发明设计人 ERIK SANNE;FREDDIE HANSSON;

    申请日2014-08-20

  • 分类号C01B33/141;C01B33/145;D21H17/37;D21H17/68;D21H21/10;

  • 国家 BR

  • 入库时间 2022-08-21 13:39:57

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