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A method of producing integral components based on expanded polystyrene with built-in functional and/or decorative elements

机译:一种基于具有内置功能和/或装饰元素的发泡聚苯乙烯生产整体组件的方法

摘要

The method of producing integral components lies in the fact that the mould is filled with the decorative and/or functional elements, whose contact surface disposed within the mould is in advance provided with an adhesive coating from a liquid prepolymer based on polyesters or polyether urethanes, based on butadiene and styrene, butadiene and acrylonitrile and/or a prepolymer based on other monomers containing terminal NCO groups in an amount of 0.7 to 3.0 weight parts, preferably 1.2 to 2.2% weight parts per 100 weight parts of prepolymer; the remaining mould space is filled with pre-foamed expanded polystyrene beads, and the product prepared this way is treated with water from saturated water vapour, thus forming a base of expanded polystyrene from the pre-foamed beads and, at the same time, a solid polymer is formed at the interface of the base and the functional and/or decorative element by the action of water on the terminal NCO group of the adhesive coating from the liquid prepolymer. The NCO groups of the prepolymer are, prior to being applied on the bonded surface, preferably masked by the addition of amino or nitro compounds, such as caprolactam, secondary amines, compounds with a phenolic nucleus, optionally by the addition of other masking agents capable of releasing NCO groups at an elevated temperature.
机译:生产整体部件的方法的事实在于,模具中充满了装饰性和/或功能性元素,模具和/或功能性元素的接触面预先设置在由基于聚酯或聚醚氨基甲酸酯的液态预聚物制成的粘合剂涂层中,基于丁二烯和苯乙烯,丁二烯和丙烯腈和/或基于包含端NCO基团的其他单体的预聚物,其相对于每100重量份的预聚物为0.7至3.0重量份,优选1.2至2.2重量份;剩余的模具空间中充满了预发泡的发泡聚苯乙烯珠,然后用饱和水蒸气中的水处理以此方式制备的产品,从而由预发泡的珠形成了发泡聚苯乙烯的基质,同时,通过水对液态预聚物在粘合剂涂层的末端NCO基团上的作用,在基体与功能和/或装饰元素的界面处形成了固态聚合物。预聚物的NCO基团在施加到粘合表面上之前,最好先通过添加氨基或硝基化合物(例如己内酰胺,仲胺,具有酚核的化合物)来掩蔽,也可以选择通过添加其他能够掩盖力的掩蔽剂来掩盖在高温下释放NCO基团的过程。

著录项

  • 公开/公告号CZ306893B6

    专利类型

  • 公开/公告日2017-08-30

    原文格式PDF

  • 申请/专利权人 UNIVERZITA TOMÁŠE BATI VE ZLÍNĚ;

    申请/专利号CZ20120000120

  • 发明设计人 JIŘÍ KUBĚNA;PETR BRIŠ;

    申请日2012-02-20

  • 分类号B29C44/44;B29C44/12;B29C44/04;B32B3/14;B32B3/22;C08J9/22;C08J5/12;

  • 国家 CZ

  • 入库时间 2022-08-21 13:39:32

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