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POLYCONDENSATION CATALYST FOR POLYESTER PREPARATION AND PREPARATION OF POLYESTER USING POLYCONDENSATION CATALYST FOR POLYESTER PREPARATION

机译:用于聚酯制备的缩聚催化剂以及用于聚酯制备的缩聚催化剂

摘要

The invention provides a polycondensation catalyst for producing polyester by an esterification reaction or a transesterification reaction between a dicarboxylic acid or an ester-forming derivative thereof and a glycol, wherein the polycondensation catalyst comprises particles of a solid base having on the surfaces an inner coating layer of titanic acid in an amount of from 0.1 to 50 parts by weight in terms of TiO 2 per 100 parts by weight of the solid base, and an outer coating layer either of an oxide of at least one element selected from aluminum, zirconium and silicon, or of a composite oxide of at least two elements selected from aluminum, zirconium and silicon on the surface of the inner coating layer in an amount of from 1 to 50 parts by weight per 100 parts by weight of the solid base.
机译:本发明提供了一种通过二羧酸或其成酯衍生物与二元醇之间的酯化反应或酯交换反应生产聚酯的缩聚催化剂,其中该缩聚催化剂包括在表面上具有内涂层的固体基质颗粒。相对于每100重量份固体碱,钛酸的量为TiO 2的0.1至50重量份,以及外涂层,所述外涂层由选自铝,锆和硅中的至少一种元素的氧化物组成每100重量份的固体碱为1〜50重量份,或者为内涂层表面上的选自铝,锆和硅中的至少两种元素的复合氧化物。

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