The invention relates to method of synthesis of phenol-aniline-formaldehyde resins using heterogeneous base catalyst having a polymeric backbone. The catalyst comprises of a tertiary amine moiety as the reactive functional group present on the crosslinked polymer backbone. Heterogeneous catalyst of the present invention can be removed easily by filtration and available for re-use without loss in catalytic activity.[IN-DEL-2010-02771A]
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