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Ammonium ionic liquids with anion of natural origin and method for producing them and their application as feeding deterrents

机译:具有天然阴离子的铵离子液体及其制备方法及其在饲料中的应用

摘要

the subject invention are liquids with ammonium ion anionem of natural origin and their manufacture and use as deterentu00f3w nutrients.ammonium ionic liquids of the general formula 1 in which the substituents r1 and r2 means alkyl containing 1 to 22 carbon atoms, or a benzyl substituent, and a means anion of natural origin, which are the source of triglycerides contained in vegetable or animal fats.the way they receive is that quaternary hydroxide ammonium undergo reaction with the fat of natural origin in the mole ratio of hydroxide to fat equal 3: 0.8 - 1.3 in the environment of drugorzu0119dowego, favourably, 2-propanol, at a temperature from 25 to 8 zero, advantageously in 80u00b0c during 1 - 24 hours, after which the vaporized solvent.and the resulting system is extracted in the organic solvent - water, dichloromethane, hexane - preferably chloroform, water and organic solvent vaporized, and resulting product, not containing impurities, dried under reduced pressure at a temperature from 30 to 80u00b0c during 1 - 24 hours.application of ionic liquids was also revealed amoniowych of general formula 1, as detergents, nutrients.
机译:本发明是天然来源的具有铵离子阴离子的液体及其制造和用作洗涤剂的营养物。通式1的铵离子液体,其中取代基r1和r2表示含1-22个碳原子的烷基,或苄基取代基和一种天然来源的阴离子,是植物或动物脂肪中所含甘油三酸酯的来源。它们的接收方式是季铵氢氧化物与天然来源的脂肪发生反应,氢氧化物与脂肪的摩尔比等于3 :在drugorz u0119dowego,有利的是2-丙醇,温度为25至8零的环境中,最好在80 u00b0c中,在1-24小时内,在0.8-1.3的温度下,然后蒸发溶剂,然后萃取所得的系统在有机溶剂(水,二氯甲烷,己烷)(优选为氯仿)中蒸发,水和有机溶剂蒸发,所得产物(不含杂质)在减压下进行减压干燥在1至24小时内的温度从30至80。离子液体的应用还揭示了通式1的铵盐,可作为洗涤剂,养分。

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