首页> 外国专利> New cyclobutane-1,1-dicarboxylate platinum(II) complexes with 5,7-disubstituted-1,2,4-triazole1,5-apyrimidines and method for producing them

New cyclobutane-1,1-dicarboxylate platinum(II) complexes with 5,7-disubstituted-1,2,4-triazole1,5-apyrimidines and method for producing them

机译:与5,7-二取代-1,2,4-三唑[1,5-a]嘧啶的新型环丁烷-1,1-二羧酸铂(II)配合物及其制备方法

摘要

the subject of new platinum (ii) complexes dikarboksylowe with 5,7 - dimethyl - 1,2,4 triazolo [1,5-a] pirymidynu0105 (dmtp) or 7 - isobutyl - 5 - methyl - 1,2,4 triazolo [1,5-a] pirymidynu0105 (ibmtp) or 5.7 - ditertbutylo - 1,2,4 triazolo [1,5-a] pirymidynu0105 (dbtp) model respectively: [pt (1,1 - cbdc) (dmtp) 2] [pt (1,1 - cbdc) (ibmtp) 2] and [pt (1,1 - cbdc) (dbtp) 2] and 1,1 - cbdc means dianion cyklobutano - 11 - dikarboksylowy.the application also includes a way to produce new dikarboksylowych complexes of platinum (ii) with that in mixtures of acetone and water per volume of 9: 1 to 1: 5, the cis - [pti2 (dmtp) 2] or cis - [pti2 (ibmtp) 2] or cis - [pti2 (dbtp) 2] and cyklobutano - 11 - dikarboksylan silver in a mole ratio of 1: 1, respectively, and without access to a light mixing for a period of from 20 to 100 hours, after which the mixture poreakcyjnu0105 odwirowuje, separated liquid decanted and the clear solution is concentrated in the air stream at a temperature of between 15 oc to 25 degrees celsius, after what drought by liofilizacje.
机译:新的铂(ii)与5,7-二甲基-1,2,4三唑[1,5-a] pirymidyn u0105(dmtp)或7-异丁基-5-甲基-1,2,4络合物dikarboksylowe的主题triazolo [1,5-a] pirymidyn u0105(ibmtp)或5.7-二叔丁基-1,2,4 triazolo [1,5-a] pirymidyn u0105(dbtp)模型:[pt(1,1-cbdc) (dmtp)2] [pt(1,1-cbdc)(ibmtp)2]和[pt(1,1-cbdc)(dbtp)2]和1,1-cbdc表示双阴离子cyklobutano-11-dikarboksylowy.application还包括一种生产新的铂(ii)的dikarboksylowych络合物的方法,该络合物是丙酮和水的体积比为9:1至1:5的顺式-[pti2(dmtp)2]或顺式-[pti2(ibmtp )2]或顺式-[pti2(dbtp)2]和cyklobutano-11-dikarboksylan银,其摩尔比分别为1:1,并且在20到100小时的时间内没有轻度混合,之后混合物混合物,倒出分离出的液体,将澄清溶液浓缩到空气流中,温度为在liofilizacje干旱之后,温度介于15摄氏度至25摄氏度之间。

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