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Method for obtaining ammonium ionic liquids with cation derivative of betaine and nonenoate anion and their application as herbicides

机译:甜菜碱和壬烯酸根阳离子衍生物制取铵离子液体的方法及其在除草剂中的应用

摘要

the object of the application is to receive liquid from kationem way amoniowych ionic betaine derivative and anionem nonanianowym and their use as herbicides.process to obtain liquid ion with kationem betaine derivative and anionem nonanianowym of general formula 1 in which r1 is a substituent prostou0142au0144cuchowy of carbon chain length from one to 18 carbon atoms, or a substituted or cocoamidopropylowy, alkiloamidopropylowy r2 means substituent prostou0142au0144cuchowy of carbon chain length from one to 18 carbon atoms.however, y means the methylene (- ch2 -) or 2 - hydroksypropylenowy [- ch2 - ch (oh) - ch2 -], is that halide derivative of general formula 2, betaine, in which r1 is substituted prostou0142au0144cuchowy of carbon chain length from one to 18 carbon atoms, or share awnik cocoamidopropylowy or alkiloamidopropylowy,r2 means a substituent prostou0142au0144cuchowy of carbon chain length from one to 18 carbon atoms, and y means a methylene (- ch2 -) or 2 - hydroksypropylenowy [- ch2 - ch (oh) - ch2 -) undergo reaction of nitrate with sodium salt or potasowu0105, or lithium, or amo new nonanoic acid in a mole ratio of acid halide to salt from 1: 0.9 to 1: 1.1, preferably 1: 1at the 100u00b0c, favourably 20u00b0c, in an organic solvent from the group of: methanol, ethanol, propanol, isopropanol, butanol, or their mixture, and with the organic solvent is formed odsu0105cza inorganic by-product of filtrate vaporized solvent, and produ kt reaction is dried.the application includes application of liquid ion kationem betaine derivative and anionem nonanianowym as herbicides.
机译:本申请的目的是从阳离子化甜菜碱离子甜菜碱衍生物和阴离子非壬基诺夫灵接收液体,并将其用作除草剂。用通式1的阳离子化甜菜碱衍生物和非阴离子基诺夫农碱获得液态离子的方法,其中r1是取代基prosto u0142a碳原子长度为1至18的碳原子,或取代或椰油酰胺基丙基,r 2表示取代基,碳原子长度为1至18的碳,但y表示亚甲基(-ch2-)或2-羟丙基丙基-[ch2-ch(oh)-ch2-]是通式2的甜菜碱的卤化物衍生物,其中r1取代有1至18个碳原子的碳原子长的prosto u0142a u0144共享awnik cocoamidopropylowy或alkiloamidopropylowy,r2表示取代基,其碳链长度为1至18个碳原子,y表示亚甲基(-ch2-)或2-羟基y-异丙醇[-ch2-ch(oh)-ch2-)进行硝酸盐与钠盐或磷酸钾或锂或氨基新壬酸的反应,酰卤与盐的摩尔比为1:0.9至1:1.1在选自甲醇,乙醇,丙醇,异丙醇,丁醇或它们的混合物的有机溶剂中,优选在100,优选20:1,优选1:1的条件下与有机溶剂形成ods滤液蒸发的溶剂的产物,干燥产物的反应。其应用包括液态离子型阳离子甜菜碱衍生物和阴离子型壬二酸阴离子除草剂的应用。

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