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METHOD FOR PRODUCING SURFACE-MODIFIED SILICA NANOPARTICLES, AND SURFACE-MODIFIED SILICA NANOPARTICLES

机译:制备表面改性的二氧化硅纳米粒子的方法和表面改性的二氧化硅纳米粒子

摘要

[Problem] To provide a dispersion containing surface-modified silica nanoparticles highly dispersed in an organic dispersion medium and also having high transparency and storage stability. [Solution] Disclosed is a method for producing surface-modified silica nanoparticles comprising: preparing a first silica nanoparticle dispersion containing silica nanoparticles and an aqueous dispersion medium; replacing the aqueous dispersion medium in the first silica nanoparticle dispersion with an organic dispersion medium comprising at least one selected from cyclic esters or cyclic amides, to obtain a second silica nanoparticle dispersion; and mixing the second silica nanoparticle dispersion with a silane coupling agent represented by the formula (1): (each R 1 is independently a hydrocarbon group of C 1 to C 20 and R 2 is a hydrocarbon group of C 1 to C 3 ), to modify the surface of the silica nanoparticles.
机译:[问题]提供一种分散体,该分散体包含高度分散在有机分散介质中并且还具有高透明性和储存稳定性的表面改性的二氧化硅纳米粒子。 [解决方案]公开了一种表面改性二氧化硅纳米粒子的制造方法,其包括:制备含有二氧化硅纳米粒子和水分散介质的第一二氧化硅纳米粒子分散液;用包含选自环酯或环状酰胺中的至少一种的有机分散介质代替第一二氧化硅纳米颗粒分散液中的水分散介质,得到第二二氧化硅纳米颗粒分散液;将第二二氧化硅纳米颗粒分散体与式(1)表示的硅烷偶联剂混合:(每个R 1独立地为C 1至C 20的烃基,并且R 2为C 1至C 3的烃基),以改性二氧化硅纳米粒子的表面。

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