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Process of manufacturing comb polymers by drying and then functionalization of the main (meth) acrylic chain, polymers obtained and their use

机译:通过干燥然后官能化丙烯酸主(甲基)链制造梳形聚合物的方法,获得的聚合物及其用途

摘要

Process for manufacturing comb polymers having a (meth) acrylic main chain and polyoxyalkylated side groups, characterized in that it consists of: a) making a solution containing at least one homopolymer of (meth) acrylic acid and / or at least a copolymer of the (meth) acrylic acid with at least one other monomer, b) drying the solution obtained in step a), in order to obtain a homopolymer of the (meth) acrylic acid in the dry state and / or a copolymer of the acid ( met) acrylic with at least one other monomer in the dry state, c) mixing the product in the dry state obtained according to step b) with at least one molten alkoxypolyoxyalkylene glycol and / or at least one molten alkoxypolyoxyalkylene amine and / or at least one alkylene oxide in a liquid or gaseous state, d) then functionalize the homopolymer and / or the copolymer of (meth) acrylic acid by: - esterification with at least one alkoxypolyoxyalkylene glycol, which is preferred It is a methoxy polyoxyalkylene glycol, most preferably a methoxy polyoxyethylene glycol, - and / or amidification with at least one alkoxypolyoxyalkylene amine, which is preferably a methoxy polyoxyalkylene amine, most preferably a methoxy polyoxyethylene amine, - and / or ethoxylation with at least one alkylene oxide, which is preferably an ethylene oxide, or propylene oxide, or mixtures thereof.
机译:具有(甲基)丙烯酸主链和聚氧烷基化侧基的梳形聚合物的制造方法,其特征在于,该方法包括:a)制备包含至少一种(甲基)丙烯酸均聚物和/或至少一种共聚物的溶液。 (甲基)丙烯酸与至少一种其他单体,b)干燥步骤a)中获得的溶液,以获得干燥状态的(甲基)丙烯酸的均聚物和/或该酸的共聚物( )丙烯酸与至少一种其他处于干燥状态的单体,c)将根据步骤b)获得的干燥状态的产物与至少一种熔融的烷氧基聚氧化烯二醇和/或至少一种熔融的烷氧基聚氧化烯胺和/或至少一种混合液态或气态的环氧烷烃,d)然后通过以下方法使(甲基)丙烯酸的均聚物和/或共聚物官能化:-用至少一种烷氧基聚氧化烯二醇进行酯化,优选为甲氧基聚氧化烯二醇。优选甲氧基聚氧化乙二醇,和/或与至少一种烷氧基聚氧化烯胺的酰胺化,优选为甲氧基聚氧化烯胺,最优选为甲氧基聚氧化乙烯胺,和/或与至少一种环氧烷的乙氧基化,优选为乙烯氧化物,或环氧丙烷或其混合物。

著录项

  • 公开/公告号ES2628020T3

    专利类型

  • 公开/公告日2017-08-01

    原文格式PDF

  • 申请/专利权人 COATEX;

    申请/专利号ES20070734529T

  • 发明设计人 MORO JEAN;SUAU JEAN-MARC;KENSICHER YVES;

    申请日2007-05-04

  • 分类号C08G81/02;C04B26/06;C08F220/28;C08F220/58;

  • 国家 ES

  • 入库时间 2022-08-21 13:35:14

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