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PREPARATION METHOD FOR MOLECULAR SIEVE MEMBRANE SUPPORT BODY

机译:分子筛膜支撑体的制备方法

摘要

A preparation method for a molecular sieve membrane support body; according to the molar ratio of magnesium, aluminium and silicon in cordierite, a nano-composite sol prepared from magnesium, aluminium, silicon, and a lanthanum sintering aid using a sol-gel method is wrapped and adhered to a dispersed micron-grade cordierite powder surface; the sol is converted into a nano-composite oxide by means of pre-sintering, and the powder is mixed with a binder and water into a mud material, extruded, and sintered into a cordierite support body; a thin film of zirconium oxide aqueous dispersion is coated onto the outside of the cordierite support body and sintered in order to obtain a molecular sieve membrane support body composed of a cordierite main support layer and a zirconium oxide thin film layer. The present method prepares a double-layer composite support body, and the base layer thin film of the support body on which the molecular sieve grows having smaller and more uniform pores and higher porosity, such that the molecular sieve membrane grown on said thin film is more uniform, and has a shorter growth period and no defects.
机译:分子筛膜载体的制备方法;根据堇青石中镁,铝和硅的摩尔比,将镁,铝,硅和镧烧结助剂通过溶胶-凝胶法制得的纳米复合溶胶包裹并粘附在分散的微米级堇青石粉末上表面;通过预烧结将溶胶转化为纳米复合氧化物,然后将粉末与粘合剂和水混合成泥状材料,挤出并烧结成堇青石载体。将氧化锆水分散体薄膜涂覆在堇青石载体的外部并烧结,以获得由堇青石主载体层和氧化锆薄膜层组成的分子筛膜载体。本方法制备了双层复合支撑体,其中生长有分子筛的支撑体的基层薄膜具有更小且更均匀的孔和更高的孔隙率,使得在所述薄膜上生长的分子筛膜为更均匀,生长期更短,无缺陷。

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