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NEW TYPE OF SAPO MOLECULAR SIEVE AND METHOD FOR SYNTHESIS THEREOF

机译:新型SAPO分子筛及其合成方法

摘要

Provided are a SAPO molecular sieve having CHA and GME intergrowth crystal phases, and a method for synthesizing same. The feature of broad peaks and sharp peaks coexisting is apparent in the XRD diffraction spectrogram of the SAPO molecular sieve, the inorganic framework thereof having the chemical composition (SixAlyPz)O2, wherein x, y, and z represent the mole fractions of Si, Al, and P, respectively, having the ranges of x=0.01 to 0.28, y=0.35 to 0.55, and z=0.28 to 0.50, respectively, and x+y+z=1. The molecular sieve may serve as a catalyst for an acid catalysis reaction, such as a methanol-to-olefins reaction; a reductive elimination reaction is selected for NOx, and also may be used for the adsorption and isolation of N2, CH4, and CO2.
机译:提供了具有CHA和GME共生晶体相的SAPO分子筛及其合成方法。在具有化学组成(Si x Al y P)的SAPO分子筛的XRD衍射谱图中,宽峰和尖峰并存的特征显而易见。 z )O 2 ,其中x,y和z分别表示Si,Al和P的摩尔分数,范围为x = 0.01至0.28, y = 0.35至0.55,z = 0.28至0.50,x + y + z = 1。分子筛可以用作酸催化反应的催化剂,例如甲醇制烯烃的反应。 NO x 的还原消除反应被选择,也可用于N 2 ,CH 4 和CO的吸附和分离。 2

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