首页> 外国专利> PREPARATION METHOD OF THREE-DIMENSIONAL CARBON NANOTUBE/NITROGEN-DOPED GRAPHENE/SULFUR ELECTRODE SLICE

PREPARATION METHOD OF THREE-DIMENSIONAL CARBON NANOTUBE/NITROGEN-DOPED GRAPHENE/SULFUR ELECTRODE SLICE

机译:三维碳纳米管/掺氮石墨烯/硫电极片的制备方法

摘要

sb /sb /sb /A three-dimensional carbon nanotube/nitrogen-doped graphene/sulfur electrode slice comprises the following steps of: step (1): adding carbon nanotubes, graphite oxide and polyacrylonitrile to N-methyl pyrrolidone, performing ultrasonic treatment, coating an aluminium foil with mixed slurry, and performing vacuum drying to obtain an electrode slice; step (2): putting the obtained electrode slice into a muffle furnace under the protection of ammonia gas, heating to 400-500℃, and naturally cooling; and step (3): completely inserting the electrode slice obtained in the step (2) into a Na2S2O3 solution, and slowly dropwise adding hydrochloric acid to the solution until the PH value of the solution reaches 6.5-7.5, and then taking out the electrode slice, and drying the electrode slice to obtain a positive plate. The prepared electrode slice can be directly applied to the positive electrode of a lithium-sulfur battery without adding a conductive agent and a binder, thus greatly lowering the cost of the electrode.
机译:三维碳纳米管/掺氮石墨烯/硫电极片包括以下步骤:步骤(1):将碳纳米管,氧化石墨和聚丙烯腈添加到N-甲基吡咯烷酮中,进行超声波处理,涂覆混合浆料的铝箔,进行真空干燥而得到电极片。步骤(2):将得到的电极片置于氨气保护下的马弗炉中,加热至400-500℃,自然冷却。步骤(3):将步骤(2)中得到的电极片完全插入Na 2 S 2 O 3溶液中,并向溶液中缓慢滴加盐酸直至溶液的PH值达到6.5-7.5,然后取出电极切片,并干燥电极切片以获得正极板。所制备的电极片可以直接应用于锂硫电池的正极,而无需添加导电剂和粘结剂,从而大大降低了电极的成本。

著录项

  • 公开/公告号WO2017139996A1

    专利类型

  • 公开/公告日2017-08-24

    原文格式PDF

  • 申请/专利权人 XIAO LIFANG;

    申请/专利号WO2016CN74195

  • 发明设计人 ZHONG LINGLONG;

    申请日2016-02-21

  • 分类号H01M4/36;H01M4/38;H01M4/583;H01M4/139;H01M10/052;

  • 国家 WO

  • 入库时间 2022-08-21 13:30:04

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