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GRAPHENE MICROSHEET MASTER BATCH FOR ENHANCING BIOPLASTIC AND PREPARATION METHOD THEREOF

机译:增强生物塑料的石墨烯微批料及其制备方法

摘要

Disclosed in the present invention are a graphene microsheet master batch for enhancing bioplastics and a preparation method thereof. The graphene microsheet/polylactic acid composite master batch is obtained by conveying lactic acid monomers between graphite layers by means of a solvent to obtain modified graphite, adding a polycondensation initiator, subjecting the lactic acid monomers to a polymerization reaction to obtain polylactic acid macromolecules between the graphite layers in situ, such that the distance between the graphite layers is increased and the acting force between the graphite layers is reduced, and subjecting the obtained alternately stacked composite materials of graphene microsheet/polylactic acid macromolecules to shearing, stripping, extrusion and pelletization. As cheap graphite is employed as a raw material in the present invention, the production cost can be effectively reduced, and the obtained master batch is of an alternately stacked and wrapped structure of graphene microsheets and polylactic acid, such that the master batch has the flexibility and the excellent mechanical performance of graphene, and thus can improve the defects of bioplastics, namely that they have low strength, poor high-temperature resistance and poor hot workability.
机译:本发明公开了一种用于增强生物塑料的石墨烯微片母料及其制备方法。石墨烯微片/聚乳酸复合母料是通过以下方式获得的:通过使用溶剂在石墨层之间输送乳酸单体以获得改性的石墨,添加缩聚引发剂,使乳酸单体进行聚合反应以获得在其之间的聚乳酸大分子。原位形成石墨层,从而增加石墨层之间的距离并减小石墨层之间的作用力,并对所得的石墨烯微片/聚乳酸大分子交替堆叠的复合材料进行剪切,剥离,挤压和造粒。由于本发明采用廉价的石墨为原料,可以有效降低生产成本,所得母料为石墨烯微片和聚乳酸的交替堆叠包裹结构,使母料具有柔韧性。以及石墨烯的优异机械性能,因此可以改善生物塑料的缺陷,即它们的强度低,耐高温性差和热加工性差。

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