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METHOD FOR PRODUCING NITROGEN-CONTAINING AROMATIC AMIDE, METHOD FOR PRODUCING PYRROLE-IMIDAZOLE POLYAMIDE, AND COMPOUND

机译:含氮芳香酰胺的制造方法,吡咯-咪唑聚酰胺的制造方法及化合物

摘要

[Problem] Provided are: a method for producing a nitrogen-containing aromatic amide, in which method a monomer unit obtained under mild reaction conditions can be used, and which is performed by the catalytic formation of amide linkages; and a method for producing a pyrrole-imidazole polyamide. [Solution] [1] A method for producing a nitrogen-containing aromatic amide, the method comprising a step for reacting compound 1 represented by general formula (1) with compound 2 represented by general formula (2) in the presence of a transition metal catalyst and a base to obtain compound 3 represented by general formula (3), [2] a method for producing a pyrrole-imidazole polyamide using compound 3 obtained by the method described in [1], and [3] a compound represented by general formula (2aa), general formula (2ab), general formula (2ac), or general formula (2ad).
机译:[问题]本发明提供一种含氮芳香族酰胺的制造方法,该方法可以使用在温和的反应条件下得到的单体单元,并且通过催化形成酰胺键来进行。以及制备吡咯-咪唑聚酰胺的方法。 [解决方案] [1]一种含氮芳族酰胺的制造方法,该方法包括使通式(1)表示的化合物1与通式(2)表示的化合物2在过渡金属存在下反应的步骤。催化剂和碱,以得到通式(3)表示的化合物3,[2]一种使用通过[1]所述的方法获得的化合物3制备吡咯-咪唑聚酰胺的方法,和[3]一种由通式表示的化合物式(2aa),通式(2ab),通式(2ac)或通式(2ad)。

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