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NITROGEN-DOPED GRAPHENE COATED NANO-SULFUR ANODE COMPOSITE MATERIAL AND PREPARATION METHOD AND APPLICATION THEREOF

机译:掺氮石墨烯包覆的纳米硫阳极复合材料及其制备方法和应用

摘要

The present invention relates to a nitrogen doped graphene-coated nano-sulfur positive electrode composite material, a manufacturing method and an application thereof. Wherein the composite material is a three-dimensional conduction network formed by overlapping with each other by nitrogen doping grains; And nano sulfur particles uniformly covered with a nitrogen doping graphene monolayer. The composite material manufacturing method comprises dispersing nitrogen doping graphene in a liquid phase reaction system containing at least a sulfur raw material and an acid, precipitating nano sulfur particles through a distal chemical reaction between sulfur raw material and an acid to obtain a target product. INDUSTRIAL APPLICABILITY The composite material of the present invention has high conductivity, high utilization ratio and rate characteristics of sulfur, effectively suppressing the dissolution and reciprocating effect in the lithium sulfur battery, improving the cyclic stability of the battery, and improving the nitrogen doped graphene- Is characterized by high capacity, high circulation stability, and high rate characteristics, and the production process of the composite material is simple, and the cost is reduced, which is suitable for large-scale production.
机译:氮掺杂石墨烯包覆的纳米硫正电极复合材料及其制造方法和应用。其中,复合材料是通过氮掺杂晶粒相互重叠而形成的三维导电网络。并且纳米硫颗粒均匀地覆盖有氮掺杂石墨烯单层。该复合材料的制造方法包括将氮掺杂石墨烯分散在至少包含硫原料和酸的液相反应体系中,通过硫原料和酸之间的远侧化学反应使纳米硫颗粒沉淀以获得目标产物。工业实用性本发明的复合材料具有高电导率,硫的高利用率和速率特性,有效地抑制了锂硫电池中的溶解和往复作用,改善了电池的循环稳定性,并改善了氮掺杂石墨烯-具有容量大,循环稳定性高,倍率高的特点,复合材料的生产工艺简单,降低了成本,适合大规模生产。

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