首页> 外国专利> IONIC BLOCK COPOLYMER, CARBON NANOTUBE SUPPORT, CARBON NANOTUBE-GRAPHENE OXIDE COMPOSITE AND METAL CATALYST

IONIC BLOCK COPOLYMER, CARBON NANOTUBE SUPPORT, CARBON NANOTUBE-GRAPHENE OXIDE COMPOSITE AND METAL CATALYST

机译:离子嵌段共聚物,碳纳米管支持物,碳纳米管-氧化石墨复合材料和金属催化剂

摘要

An objective of the present invention is to provide an ionic block copolymer which can inhibit aggregation of carbon-based materials. Other objective of the present invention is to provide a carbon nanotube support and a carbon nanotube-graphene oxide composite which can inhibit aggregation phenomena and maintaining dispersibility of metal nanoparticles. Another objective of the present invention is to provide a metal catalyst which can improve catalytic characteristics by inhibiting the aggregation phenomena and maintaining dispersibility of the metal nanoparticles. The ionic block copolymer represented by the following structural formula 1 is disclosed. In structural formula 1, the backbone has acryl or methacryl as a basic structure; a) R_1 is one selected from the group consisting of an alkyl group, a benzyl group, a cyclohexyl group and a perfuryl group in case of hydrophobic properties; b) R_1 is one selected from the group consisting of an alkyl acid group, an ethylene glycol group and an alkyl alkoxy group in case of hydrophilic properties; R_2 is one selected from a halogen group consisting of bromine, chloride and iodine; R_3 is one selected from a group consisting of a benzyl group, a naphthalene group, a coumarin group, a rhodamine group, a fluorocene group, a pyrenyl group, a pentacene group, a thiophene group and an aniline group; n is an integer of 10 to 50; m is an integer within a range of m = n = 100; x is an integer greater than or equal to y; and y is an integer equal to or greater than 1.;COPYRIGHT KIPO 2017
机译:本发明的目的是提供一种可以抑制碳基材料的聚集的离子嵌段共聚物。本发明的另一个目的是提供可以抑制聚集现象并保持金属纳米颗粒的分散性的碳纳米管载体和碳纳米管-氧化石墨烯复合物。本发明的另一个目的是提供一种金属催化剂,其可以通过抑制聚集现象并保持金属纳米颗粒的分散性来改善催化特性。公开了由以下结构式1表示的离子嵌段共聚物。在结构式1中,主链具有丙烯酸或甲基丙烯酸作为基本结构。 a)在具有疏水性的情况下,R_1选自烷基,苄基,环己基和全呋喃基中的一个; b)在具有亲水性的情况下,R_1选自烷基,乙二醇基和烷基烷氧基。 R_2是选自由溴,氯和碘组成的卤素基团中的一种; R_3是选自由苄基,萘基,香豆素基,若丹明基,芴基,a基,并五苯基,噻吩基和苯胺基组成的组中的一个。 n为10至50的整数; m是m≤n≤100的整数。 x是大于或等于y的整数; y为1以上的整数; COPYRIGHT KIPO 2017

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