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/ Inorganic-organic hybrid particles for absorbing simultaneously hydrophobic and hydrophillic pollutants from water

机译:/无机-有机杂化颗粒,可同时吸收水中的疏水性和亲水性污染物

摘要

The present invention relates to an alkoxysilane functionalized amphipathic precursor having hyperbranched cross-linking between alkoxysilane functionalized precursors having a structure of the following formula (1), wherein a part of the alkoxysilane functional group of the amphipathic precursor is chemically bonded to silica particles or metal oxide nanoparticles Organic hybrid particles for removing pollutants. [Chemical Formula 1] (In the formula 1, Wherein A is a substance comprising a hydrophilic segment and two or more hydroxyl groups (-OH), wherein an isocyanate group (-CN) of the B and a urethane bond (-OCONH-) are formed; Wherein B is a substance comprising a hydrophobic segment and two or more isocyanate groups (-CN), one isocyanate group reacts with the hydroxy group of A to form a urethane bond, and the other is a hydroxyl group or amine React with the group to form a urethane bond or a urea (-NHCONH-) bond; Wherein C is a substance comprising a hydroxyl group and an alkoxysilane group, or an amine group and an alkoxysilane group, wherein a hydroxyl group or an amine group reacts with the isocyanate group of B to form a urethane bond or a urea bond; n is an integer of 1 or more.)
机译:本发明涉及在具有下式(1)的结构的烷氧基硅烷官能化的前体之间具有超支化交联的烷氧基硅烷官能化的两亲性前体,其中,两亲性前体的烷氧基硅烷官能团的一部分化学键合到二氧化硅粒子或金属上氧化物纳米颗粒用于去除污染物的有机杂化颗粒。 [化学式1](式1中,A为包含亲水链段和两个或更多个羟基(-OH)的物质,其中B的异氰酸酯基(-CN)和氨基甲酸酯键(-OCONH- ;其中B是包含疏水链段和两个或更多个异氰酸酯基团(-CN)的物质,一个异氰酸酯基团与A的羟基反应形成氨基甲酸酯键,另一个是羟基或胺反应。其中C为包含羟基和烷氧基硅烷基团或胺基和烷氧基硅烷基团的物质,其中羟基或胺基团反应;与B的异氰酸酯基团形成氨基甲酸酯键或脲键; n是1或更大的整数。

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