首页> 外国专利> / - PALLADIUM CATALYST SYSTEM COMPRISING ZWITTERION AND/OR ACID-FUNCTIONALIZED IONIC LIQUID

/ - PALLADIUM CATALYST SYSTEM COMPRISING ZWITTERION AND/OR ACID-FUNCTIONALIZED IONIC LIQUID

机译:/-包含两性离子和/或酸功能化离子液体的钯催化剂体系

摘要

The present invention, specifically, palladium (Pd), zwitterions, and / or acid on the catalyst system relates to a catalyst system comprising a functionalized ionic liquid and at least one phosphine ligand, wherein the Pd catalyst Pd (CH 3 COO) 2, PdCl 2, Pd (CH 3 COCHCOCH 3), Pd (CF 3 COO) 2, Pd (PPh 3) 4 or Pd 2 (dibenzylideneacetone) by the complex precursor, such as 3 It can be provided. Such catalyst systems are, for example, in the production of methyl propionate and / or propanoyl acid, optionally in the step to form methyl methacrylate and / or methacrylic acid, such as alkoxy carbonylation reaction, carboxylated reaction and / or it may be used in the copolymer reaction. The catalyst system according to the present invention is suitable for the reaction and the supported ionic liquid SILP purpose of forming a separable product and a catalyst phase.
机译:具体而言,本发明涉及催化剂体系上的钯(Pd),两性离子和/或酸,涉及包含官能化离子液体和至少一种膦配体的催化剂体系,其中Pd催化剂 Pd( CH 3 COO)2, PdCl 2,Pd(CH 3 COCHCOCH 3),Pd(CF 3 COO)2,Pd(PPh 3)4或Pd 2 (可以提供复杂的前体,例如 3 。这样的催化剂体系例如在丙酸甲酯和/或丙酸的生产中,任选地在形成甲基丙烯酸甲酯和/或甲基丙烯酸的步骤中,例如烷氧基羰基化反应,羧化反应和/或可以用于共聚物反应。根据本发明的催化剂体系适合于反应和负载型离子液体SILP的目的,以形成可分离的产物和催化剂相。

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