FIELD: chemistry.;SUBSTANCE: invention relates to a method for preparation of fulleropyrrolidines that can be used as complexing agents, sorbents, biologically active compounds, as well as for creation of new materials with specified electronic, magnetic, and optical properties. A method for selective preparation of isopropyl-5'-aryl-1'H-pyrrolidino[3',4':1,9](C60-Ih)[5,6]fullerene-2'-carboxylates of the general formula is characterised by C60-fullerene reaction with ethyl isocyanoacetate of the formulaEtO2CCH2N+≡C in chlorobenzene under the action of the Ti(OiPr)4 catalyst in the presence of ArMgBr (where Ar = Ph, 2-MePh), taken in the molar ratioof C60:Isocyanoacetate:Ti(OiPr)4:ArMgBr = 1:(2-6):(1-5):(6-10), at a temperature of 100°C for 5-30 minutes.;EFFECT: improved method for preparation of these compounds.;1 tbl, 1 ex
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机译：技术领域本发明涉及一种制备全吡咯烷的方法，所述全吡咯烷可用作络合剂，吸附剂，生物活性化合物，以及用于制备具有特定电子，磁性和光学性质的新材料。一种选择性制备异丙基-5'-芳基-1'H-吡咯烷基[3'，4'：1,9]（C 60- I h ）的方法通式的[5,6]富勒烯2'-羧酸盐的特征是C作用下， 60 -富勒烯与式EtO 2 CCH 2 N + ≡C的异氰基乙酸乙酯在氯苯中的反应ArMgBr（其中Ar = Ph，2-MePh）存在下Ti（OiPr） 4 催化剂的合成，以C 60 ：异氰基乙酸酯：Ti（ OiPr） 4 ：ArMgBr = 1：（2-6）:( 1-5）:( 6-10），在100°C的温度下保持5-30分钟;效果：改善这些化合物的制备方法。; 1 tbl，1 ex
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