首页> 外国专利> POLYESTER / PRIMARY / COHESIVE-IMPRESSED COHESIVE METAL COMPOSITE FILM, MANUFACTURING METHOD THEREOF AND PRIMARY IMPLEMENTED THEREIN

POLYESTER / PRIMARY / COHESIVE-IMPRESSED COHESIVE METAL COMPOSITE FILM, MANUFACTURING METHOD THEREOF AND PRIMARY IMPLEMENTED THEREIN

机译:聚酯/初级/粘着性粘着性金属复合膜,其制造方法及其主要实现

摘要

The object of the invention is to provide polyester / primary / metal coating composite films with good adhesion of the metal coating under dry and wet conditions. These films also form a good gas barrier: oxygen permeability less than or equal to 0.8 cc / m2 / J; permeability to water vapor less than or equal to 0.3 g / m2 / day. To this end, the invention provides a composite film comprising a polyester support, at least one coating adhering to at least one of the faces of the support and at least one layer of crosslinked primer between the support and the coating. This primer comprises at least one acrylic and / or methacrylic P1 polymer, at least one acrylic and / or methacrylic P2 polymer other than P1, at least one crosslinking agent, and, preferably, at least one water-soluble or water-dispersible polyester: P1 having a TG1 gel level ≥70% dry weight with respect to P1; P2 having a gel level TG2 ≤ TG1 and ≤ 20% dry weight, relative to P2; P1 having a free acid low acid content grafted at the surface ≥ 0.8 in meq / g of polymer; - [P2] ≤ 60% by weight on a dry basis by weight with respect to P1 + P2. The method of manufacturing this film, the primer, the articles obtained from this film, are others of the present invention.
机译:本发明的目的是提供在干燥和湿润条件下对金属涂层具有良好粘合性的聚酯/初级/金属涂层复合膜。这些薄膜还形成了良好的阻气性:氧气渗透率小于或等于0.8 cc / m2 / J;对水蒸气的渗透率小于或等于0.3克/平方米/天。为此,本发明提供了一种复合膜,该复合膜包括聚酯支撑体,至少一个粘附在支撑体至少一个面上的涂层以及在支撑体与涂层之间的至少一层交联底漆层。该底漆包含至少一种丙烯酸和/或甲基丙烯酸的P1聚合物,至少一种除P1以外的丙烯酸和/或甲基丙烯酸的P2聚合物,至少一种交联剂,以及优选至少一种水溶性或水分散性聚酯:相对于P1,TG1凝胶水平≥70%干重的P1;相对于P2,凝胶水平TG2≤TG1且干重≤20%的P2; P1具有低酸含量的游离酸,接枝到聚合物表面的当量≥0.8 meq / g; -[P2]相对于P1 + P2,以干重计≤60重量%。制造该膜的方法,底漆,从该膜获得的制品是本发明的其他方法。

著录项

  • 公开/公告号FR3042437A1

    专利类型

  • 公开/公告日2017-04-21

    原文格式PDF

  • 申请/专利权人 TORAY FILM EUROPE;

    申请/专利号FR1559896A

  • 申请日2015-10-16

  • 分类号B32B27/30;B65D65/02;C08J5/08;C08J7/04;E04B1/64;E04B1/76;

  • 国家 FR

  • 入库时间 2022-08-21 13:21:18

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