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METAL COMPLEX AND SUPPORTED METAL COMPLEX HAVING DISILOXANE AS LIGAND, PREPARATION METHOD THEREFOR, AND SUPPORTED METAL CATALYST PREPARED USING SAME

机译:以二甲恶烷为配体的金属配合物和支撑的金属配合物,其制备方法以及使用相同方法制备的支撑金属催化剂

摘要

A metal complex represented by the following Formula (1): (wherein M represents palladium or platinum; L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound and an isocyanide compound; n represents an integer of 0 to 2 showing the number of the ligand; and each of R 1 to R 4 represents an organic group). The metal complex described above can be fixed on an inorganic oxide while maintaining a skeletal structure thereof to obtain a supported metal complex, and this makes it possible to allow the supported metal complex to maintain the same catalytic activity as that of the original metal complex. Also, calcining the supported metal complex obtained in the manner described above makes it possible to obtain a supported metal catalyst which is improved in catalytic activity to a greater extent than conventional supported metal catalysts.
机译:由下式(1)表示的金属络合物:(其中M表示钯或铂; L表示选自一氧化碳,烯烃化合物,胺化合物,膦化合物,N-杂环卡宾化合物,腈化合物和异氰化物的配体; n表示0的整数R 2至R 2表示配体的数目; R 1至R 4各自表示有机基团。上述金属络合物可以在保持其骨架结构的同时固定在无机氧化物上以获得负载的金属络合物,这使得可以使负载的金属络合物保持与原始金属络合物相同的催化活性。而且,通过煅烧以上述方式获得的载体金属络合物,可以获得与常规载体金属催化剂相比催化活性得到更大程度改善的载体金属催化剂。

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