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MAYENITE-TYPE COMPOUND CONTAINING IMIDE ANION, AND METHOD FOR PRODUCING SAME

机译:包含酰亚胺阴离子的蛋黄石型化合物及其制备方法

摘要

The invention related to a material that can stably hold an imide anion (NH2-) therein even in the atmosphere or in a solvent, and a method for synthesizing the material and a use of the material. A mayenite-type compound into which imide anions are incorporated at a concentration of 1 × 1018 cm-3 or more are provided. The mayenite-type compound can be produced by heating a mayenite-type compound including electrons or free oxygen ions in a cage thereof, in liquefied ammonia at 450 to 700°C and at a pressure of 30 to 100 MPa. The compound has properties such that active imide anions can be easily incorporated into the compound and the active imide anions can be easily released in the form of ammonia from the compound, and the compound has chemical stability.
机译:本发明涉及即使在大气中或在溶剂中也能稳定地保持酰亚胺阴离子(NH 2 -)的材料,以及该材料的合成方法和材料的使用。提供一种以1×10 18 cm -3 或更高的浓度掺入酰亚胺阴离子的钙铝石型化合物。钙铝石型化合物可以通过在笼中,在450至700℃的液化氨中,在30至100MPa的压力下加热包含电子或自由氧离子的钙铝石型化合物来制备。该化合物具有可以容易地将活性酰亚胺阴离子结合到化合物中并且可以容易地以氨的形式从化合物中释放出活性酰亚胺阴离子的性质,并且该化合物具有化学稳定性。

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