首页> 外国专利> METHOD OF TREATING SILICON-CONTAINING WASTEWATER AND METHOD OF UTILIZING SILICON-CONTAINING WASTEWATER, AND MOLECULAR SIEVE MANUFACTURING METHOD AND SYSTEM

METHOD OF TREATING SILICON-CONTAINING WASTEWATER AND METHOD OF UTILIZING SILICON-CONTAINING WASTEWATER, AND MOLECULAR SIEVE MANUFACTURING METHOD AND SYSTEM

机译:处理含硅废水的方法和利用含硅废水的方法以及分子筛制造方法和系统

摘要

The present invention discloses a method for the treatment of silicon-containing wastewater from the preparation of a molecular sieve or a catalyst, comprising contacting the silicon-containing wastewater with at least one acid or at least one alkali, so that at least a part of the silicon elements in the silicon-containing wastewater form a colloid. A mixture containing a colloid is thus obtained. A silicon-containing solid phase and a first liquid phase are produced by a solid-liquid separation. A solid phase and a second liquid phase are produced by a solid-liquid separation after at least a part of the metal elements in the first liquid phase form a precipitate. At least a part of the second liquid phase is subjected to electrodialysis to produce an acid liquor and/or an alkali liquor. The silicon-containing solid phase can be used as the raw material for a molecular sieve synthesis. The second liquid phase can be used as washing water in the washing process of the molecular sieve. The acid liquor can be used in the ion exchange process of the molecular sieve. The alkali liquor can be used as the alkali source in the molecular sieve synthesis. The method of the present invention can achieve a relatively high silicon recovery rate and a higher wastewater utilization rate. Basically no wastewater or an extremely low volume of wastewater is discharged. In the meanwhile, the discharged solid wastes are in a very low amount.
机译:本发明公开了一种从分子筛或催化剂的制备中处理含硅废水的方法,该方法包括使所述含硅废水与至少一种酸或至少一种碱接触,以使含硅废水中的硅元素形成胶体。由此获得含有胶体的混合物。通过固液分离产生含硅固相和第一液相。在第一液相中的至少一部分金属元素形成沉淀物之后,通过固液分离产生固相和第二液相。对第二液相的至少一部分进行电渗析以产生酸液和/或碱液。含硅固相可以用作分子筛合成的原料。第二液相可以在分子筛的洗涤过程中用作洗涤水。酸性液体可用于分子筛的离子交换过程。碱液可以用作分子筛合成中的碱源。本发明的方法可以实现较高的硅回收率和较高的废水利用率。基本上没有废水或极少量的废水被排出。同时,排出的固体废物非常少。

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