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A METHOD FOR PURIFICATION OF ORGANIC WATER-SOLUBLE COMPOUNDS FROM HYDROPHOBIC CONTAMINANTS

机译:从疏水性污染物中纯化有机水溶性化合物的方法

摘要

The subject of the invention is a method for purification of organic water-soluble compounds from hydrophobic contaminants based on the principle of nanosegregation of hydrophobic compounds (contaminants) in aqueous solutions of water-soluble compounds, followed by filtration using nanoporous filters that removes the contaminants. The purification method according to this invention is based on the findings that under certain physico-chemical conditions the contaminants neither remain molecularly dissolved nor form one macroscopic phase, but segregate into discrete nanoparticles. Given the relatively stable structure, mechanical strength and shape stability of these nanoparticles, it is possible by an appropriate choice of nanofiltration parameters to remove the nanoparticles, and thus to remove the contaminants.;The advantage of the given method is that the separation of contaminants into discrete, relatively stable, and solid (subsequently filterable) nanoparticles occurs after addition of water only, without addition of any chemicals (stabilizers, surfactants) which could present a secondary contamination and would also increase the costs of purification. The method according to this invention can reduce the content of the contaminants to levels below 0.00005% (below 0.5 ppm).
机译:本发明的主题是基于疏水性化合物(污染物)在水溶性化合物的水溶液中的纳米分离的原理,从疏水性污染物中纯化有机水溶性化合物的方法,然后使用纳米孔过滤器进行过滤以除去污染物。 。根据本发明的纯化方法是基于以下发现:在某些物理化学条件下,污染物既不保持分子溶解状态也不形成一个宏观相,而是分离成离散的纳米颗粒。鉴于相对稳定的结构,机械强度和这些纳米颗粒的形状稳定性,这是通过纳米过滤参数的适当选择可以除去所述纳米颗粒,从而除去污染物;给定方法的优点在于,污物的分离仅添加水后,就不会形成离散,相对稳定且固体(随后可过滤)的纳米颗粒,而没有添加任何可能造成二次污染并会增加纯化成本的化学物质(稳定剂,表面活性剂)。根据本发明的方法可以将污染物的含量降低至低于0.00005%的水平(低于0.5ppm)。

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