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Manufacturing method of polyimide resin, manufacturing method of polyimide film, manufacturing method of polyamic acid solution, polyimide film, and polyamic acid solution

机译:聚酰亚胺树脂的制造方法,聚酰亚胺膜的制造方法,聚酰胺酸溶液的制造方法,聚酰亚胺膜和聚酰胺酸溶液

摘要

Provided is a method of producing a polyimide resin or a polyimide coating, which is capable of producing a polyimide resin or a polyimide coating, each having excellent heat resistance and mechanical properties and having low hygroscopicity, while suppressing foaming. Provided is also a method of producing a polyamic acid solution, in which not only foaming at the time of polyimide resin production can be suppressed, but also a polyimide resin that is excellent in heat resistance and mechanical properties and low in hygroscopicity is given. Provided is further a polyimide coating and a polyamic acid solution obtained from these methods, respectively. A polyamic acid obtained from a reaction between a tetracarboxylic acid dianhydride component and a diamine component is heated in a mixed solvent composed of N,N,N',N'-tetramethylurea and at least one solvent selected from specified aprotic polar organic solvents and specified glycol ethers, to yield a polyimide resin.
机译:本发明提供一种聚酰亚胺树脂或聚酰亚胺涂层的制造方法,该方法能够抑制发泡,并且具有优异的耐热性,机械特性且吸湿性低,并且能够制造聚酰亚胺树脂或聚酰亚胺涂层。本发明还提供一种聚酰胺酸溶液的制造方法,该方法不仅可以抑制聚酰亚胺树脂制造时的发泡,而且可以提供耐热性,机械特性优异,吸湿性低的聚酰亚胺树脂。还分别提供了由这些方法获得的聚酰亚胺涂层和聚酰胺酸溶液。在由N,N,N',N'-N'-四甲基脲与至少一种选自特定非质子极性有机溶剂和特定溶剂中的混合溶剂组成的混合溶剂中加热由四羧酸二酐成分和二胺成分之间的反应获得的聚酰胺酸二醇醚,得到聚酰亚胺树脂。

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