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Rubber-based composition modifier, and vulcanized product and molded article of rubber composition to which the modifier is added

机译:橡胶基组合物改性剂,以及添加了该改性剂的橡胶组合物的硫化物和成型品

摘要

Provided are a rubber-based composition modifier that provides a vulcanizate having excellent heat resistance and ozone resistance, and a vulcanizate and a molded product of a rubber composition to which the modifier is added. 10 to 60 parts by mass of magnesium oxide with respect to 100 parts by mass of a mixed rubber component consisting of chloroprene rubber and at least one selected from ethylene / α-olefin copolymer and ethylene / α-olefin / non-conjugated polyene copolymer Rubber composition modifier containing 3 parts by weight, 3-30 parts by weight of a softener, and 30-120 parts by weight of acetylene black. However, the mixed rubber component has a Mooney viscosity at 100 ° C. measured by a method defined in JIS K6300 of 60 to 180, and the magnesium oxide has a BET specific surface area measured by a one-point method defined in JIS Z8830. 20 to 150 m 2 / g, and the softener comprises a fatty acid ester plasticizer and an unsaturated fatty acid having 10 to 24 carbon atoms having an ester bond and / or a hydroxyl group as a part of the structure, The acetylene black has a nitrogen adsorption specific surface area (N 2 SA) measured by the method defined in JIS K6217-2 of 50 to 160 m 2 / g.
机译:提供一种橡胶基组合物改性剂,其提供具有优异的耐热性和耐臭氧性的硫化橡胶,以及硫化橡胶和添加了改性剂的橡胶组合物的成型品。相对于100质量份的由氯丁橡胶和选自乙烯/α-烯烃共聚物和乙烯/α-烯烃/非共轭多烯共聚物中的至少一种的混合橡胶组分,氧化镁为10至60质量份组合物改性剂,其包含3重量份,3-30重量份的软化剂和30-120重量份的乙炔黑。然而,混合橡胶组分通过JIS K6300中定义的方法测量的在100℃下的门尼粘度为60至180,并且氧化镁具有通过JIS Z8830中定义的单点方法测量的BET比表面积。所述软化剂包括20至150m 2 / g,所述软化剂包括脂肪酸酯增塑剂和具有10-24个具有酯键和/或羟基的碳原子的不饱和脂肪酸作为所述部分的乙炔黑具有通过JIS K6217-2中定义的方法测得的氮吸附比表面积(N 2 SA)为50至160m 2 / g。

著录项

  • 公开/公告号JPWO2017086282A1

    专利类型

  • 公开/公告日2018-08-30

    原文格式PDF

  • 申请/专利权人 デンカ株式会社;

    申请/专利号JP20170551867

  • 发明设计人 小林 直紀;阿部 靖;

    申请日2016-11-15

  • 分类号C08L11;C08L23/08;C08K3/22;C08K5/10;C08K5/18;C08K5/13;C08K5/524;C08L7;C08L9;C08L23/16;C08K5/3445;

  • 国家 JP

  • 入库时间 2022-08-21 13:07:58

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