Disclosed are an apparatus for analyte sampling, and a method of analyte sampling and an analyte sampling analysis system using the same. The apparatus includes a spray unit to receive a trapping solution and an analyte sample, and to mix and spray the analyte sample and the trapping solution of an aerosol state together, a spray chamber to provide a space to primarily trap an analyte material, which is contained in the analyte sample, in the trapping solution of the aerosol state, a trapping tube to secondarily trap the analyte material, which is not trapped in the spray chamber, by receiving the analyte sample and the trapping solution in the aerosol state from the spray chamber and mixing the trapping solution with the analyte sample, a trapping container to receive the trapping solution having the analyte material trapped therein through the trapping tube, and a sample transfer unit to feed purge gas into the trapping container to transfer the trapping solution having the analyte material trapped therein to an analysis unit through a sample transfer line by the purge gas.
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